Recent Advances in the Synthesis and Polymerization of New CO_(2)-Based Cyclic  

作　　者：Matteo Lanzi Arjan W.Kleij 

机构地区：[1]Institute of Chemical Research of Catalonia(ICIQ),The Barcelona Institute of Science and Technology(BIST),Av.Països Catalans 16,43007 Tarragona,Spain [2]Catalan Institute of Research and Advanced Studies(ICREA),Pg.Lluís Companys 23,08010 Barcelona,Spain

出　　处：《Chinese Journal of Chemistry》2024年第4期430-443,共14页中国化学（英文版）

基　　金：the Cerca program/Generalitat de Catalunya,ICREA,MINECO(PID2020-112684GB-100);the Ministerio de Ciencia e Innovacion(Severo Ochoa Excellence Accreditation 2020-2023 CEX2019-000925-S)and AGAUR(2021-SGR-00853)for support.

摘　　要：Carbon dioxide can be converted into functional heterocycles known as cyclic carbonates,whose recent reactivity has been expanded towards the formation of tailor-made engineering polymers.This minireview gives an overview of the most topical developments in this area with a special focus on the synthetic methods employed to prepare these CO_(2)based synthons.In addition,their application potential in the area of polymer science using a variety of polymerization techniques is discussed that have in common the ring-opening of the carbonate monomers.Future perspectives are provided that provide impetus for the scientific communities aligning research to the use of sustainable processes for polymers from recyclable carbon sources such as CO_(2).

关 键 词：Carbon dioxide Cyclic carbonates Functional macromolecules HETEROCYCLES POLYCARBONATES Recycling Ring opening polymerization 

分 类 号：O62[理学—有机化学]