金属有机框架(MOFs)材料光解水制氢研究进展  

Progress of photohydrolysis for hydrogen production from metal-organic frameworks(MOFs)materials

作　　者：陈斯玙 钱庆荣[1] 薛珲[1] CHEN Siyu;QIAN Qingrong;XUE Hui(College of Environmental and Resource Science,College of Carbon Neutral Modern Industry,Fujian Normal University,Fuzhou 350007,China)

机构地区：[1]福建师范大学环境与资源学院、碳中和现代产业学院,福建福州350007

出　　处：《再生资源与循环经济》2024年第4期4-9,共6页Recyclable Resources and Circular Economy

基　　金：国家科技支撑计划项目(2019YFC1908203);福建省自然科学基金(2022J01650)。

摘　　要：随着全球变暖、环境污染和能源短缺等问题的日益严重,发展绿色可再生能源迫在眉睫。通过光催化分解水制备氢气是实现更高层次可持续性的理想策略。金属有机框架(MOFs)材料因其结构可控性、高孔隙性和独特的半导体特性,成为该领域的研究热点。国内外学者对其用于光解水制氢进行了大量的研究,并取得了一定的进展。系统的总结了基于MOFs材料及其复合材料的光催化剂在分解水制氢方面的应用,分析了其高效产氢的原因及可能的产氢机理,总结了MOFs基光催化剂的优势和局限,望能对开发新型高效的MOFs光催化剂提供参考。With the worsening problems of global warming,environmental pollution and energy shortage,the development of green and renewable energy sources is imminent.Hydrogen preparation by photocatalytic water splitting is an ideal strategy for achieving higher levels of sustainability.Metal-organic frameworks(MOFs)materials have become a research hotspot in this field due to their structural controllability,high porosity and unique semiconductor properties.Scholars at home and abroad have conducted a lot of research on their use for hydrogen production from photocatalytic water splitting and have made some progress.In this paper,we systematically summarize the application of photocatalysts based on MOFs materials and their composites in photocatalytic water splitting for hydrogen production,analyze the reasons for their efficient hydrogen production and possible hydrogen production mechanisms,and summarize the advantages and limitations of MOFs-based photocatalysts in hopes of providing references for the development of new and efficient MOFs photocatalysts.

关 键 词：光催化 金属有机框架材料 光解水制氢 

分 类 号：TQ032[化学工程] F113.3[经济管理—国际贸易]