导电酞菁基金属有机框架的高效电催化研究  

Conductive Phthalocyanine-Based Metal-Organic Frameworks for Efficient Electrocatalysis

作　　者：陆顺 刘元[1] 刘鸿[1] Shun Lu;Yuan Liu;Hong Liu(Chongqing Institute of Green and Intelligent Technology,Chinese Academy of Sciences,Chongqing 400715,China)

机构地区：[1]中国科学院重庆绿色智能技术研究院,重庆400715

出　　处：《化学进展》2024年第3期285-296,共12页Progress in Chemistry

基　　金：supported by the National Natural Science Foundation of China(Nos.52131003,52122007,52200076);the Specific Research Fellowship of Chinese Academy of Sciences(No.E329620101);the Natural Science Foundation of Chongqing(No.cstb2022nscq-bhx0035)~~。

摘　　要：在满足日益增长的可持续能源和环境保护需求下,开发用于多种电化学场景的新型催化剂发挥着重要作用。导电酞菁基金属有机框架(MOFs)是一类新型的层叠多孔MOFs,具有面内扩展π共轭结构,可以通过促进传质和电子/电荷转移来增强电催化活性。导电酞菁基MOFs具有优异的导电性,使其在如水、氧、二氧化碳和氮还原等各种电催化反应中非常有前景。导电酞菁基MOFs在电化学能量转换和环境研究中表现出良好的活性。本文主要关注导电酞菁基MOFs,而非其他类型的导电MOFs,并全面概述其导电机理和主要的电催化反应,还将讨论在电催化中使用导电酞菁基MOFs作为非均相催化剂的最新进展。此外,本文将探讨与导电酞菁基MOFs在电催化中的应用的挑战和展望。The development of innovative catalysts for various electrochemical scenarios is crucial in satisfying the growing demands for sustainable energy and environmental conservation.Conductive metal-organic frameworks(c-MOFs)based on phthalocyanine complexes known as phthalocyanine-based c-MOFs,have shown promising potential in electrochemical energy conversion and environmental research.These c-MOFs represent a new category of layer-stacked porous MOFs with in-plane extendedπ-conjugation structure,which can enhance electrocatalytic activity by facilitating the mass diffusion of reactants and electron/charge transfer.The exceptional promising for a variety electrocatalytic reactions,such as water,oxygen,CO2,and nitrogen conversion.In this work,we focus primarily on phthalocyanine-based c-MOFs rather than other types of c-MOFs,providing a comprehensive overview of their conductive mechanisms and main electrocatalytic reactions.We also cover recent progress in the utilization of phthalocyanine-based c-MOFs as heterogeneous catalysts in electrocatalysis.Furthermore,we explore the challenges related to the utilization of phthalocyanine-based c-MOFs in electrocatalysis.The state-of-the-art research and insights into the future perspectives of phthalocyanine-based c-MOFs as electrocatalysts are also presented and discussed.This work aim to guide the development of phthalocyanine-based c-MOF electrocatalysts with enhanced activity.

关 键 词：导电金属有机框架 酞菁基金属有机骨架 共轭结构 电催化 

分 类 号：O622.6[理学—有机化学] TB24[理学—化学]