MOFs在催化有机分子转化中的应用  

Application of MOFs in Catalytic Conversion of Organic Molecules

作　　者：李希臣 李政 彭灿 钱陈 韩雨霏 张涛 Xichen Li;Zheng Li;Can Peng;Chen Qian;Yufei Han;Tao Zhang(Department of Radiopharmaceuticals,School of Pharmacy,Nanjing Medical University,Nanjing 211166,China;Nuclear Medicine Clinical Transformation Center,Nanjing Medical University,Nanjing 210029,China)

机构地区：[1]南京医科大学药学院核药学系,南京211166 [2]南京医科大学核医药临床转化中心,南京210029

出　　处：《化学进展》2024年第3期367-375,共9页Progress in Chemistry

基　　金：国家自然科学基金项目(No.12275135);江苏省高校自然科学研究项目(No.21KJB350015);南京医科大学引进人才科研启动基金(No.NMUR20210003);南京医科大学内涵建设重点项目和南京医科大学科技发展基金(No.NMUB20210014);江苏省高校自然科学研究项目(No.22KJB350008)资助。

摘　　要：金属有机框架化合物(MOF),又称多孔性配位聚合物,是有机配体与金属离子自组装而成的一类新型有机-无机杂化多孔材料,是纳米材料的重要组成部分。与其他多孔材料相比,MOFs具有较大的比表面积、高的孔隙率以及结构和性质可调等特性,使其在非均相催化领域具有良好的应用前景。本文首先对MOFs催化的背景进行简述,然后对近年来报道的MOFs用于有机分子催化转化反应的进展进行了综述及展望,以期为MOFs催化有机反应的设计和开发提供参考。Metal-organic framework compounds(MOF),also known as porous coordination polymers,are a new type of organic-inorganic hybrid porous materials which are self-assembled from organic ligands and metal ions,and are an important part of nanomaterials.Compared to other porous materials,MOFs have a large surface area,high porosity and adjustable structure and properties,making them have a good application prospect in heterogeneous catalysis.In this paper,the background of MOFs catalysis is briefly reviewed,followed by a review and prospect of the recent progress of MOFs in catalytic conversion reactions of organic molecules,in order to provide a reference for the design and development of organic reactions catalyzed by MOFs.

关 键 词：金属有机框架材料 非均相催化 界面金属有机化学 有机分子 高附加值化学品 

分 类 号：O643.3[理学—物理化学] O627[理学—化学]