基于聚碳酸酯高耐性塑料涂料用丙烯酸乳胶的制备与研究  

The Preparation and Research of Acrylate Latex Based on Polycarbonate Highly Resistant Plastic Paint

作　　者：贾斌 曹劲松 乔永洛 申亮 Jia Bin;Cao Jinsong;Qiao Yongluo;Shen Liang(Department of Coatings and Polymers,School of Chemistry and Chemical Engineering,Jiangxi Science&Technology Normal University,Nanchang 330013,China;Jiangxi Key Laboratory of Organic Chemistry,Nanchang 330013,China;Jiangxi Provincial Engineering Research Center of Waterborne Coatings,Nanchang 330013,China)

机构地区：[1]江西科技师范大学化学化工学院涂料与高分子系,南昌330013 [2]江西省有机功能分子重点实验室,南昌330013 [3]江西省水性涂料工程研究中心,南昌330013

出　　处：《涂料工业》2024年第5期27-31,38,共6页Paint & Coatings Industry

基　　金：地区科学基金项目(51963010)。

摘　　要：为克服水性涂料在聚碳酸酯(PC)塑料上综合性能不佳的问题,以甲基丙烯酸甲酯(MMA)、苯乙烯(St)、丙烯酸丁酯(BA)为主单体,衣康酸为功能单体,引入长链烷基单体甲基丙烯酸月桂酯(LMA),以及乙酰乙酸基甲基丙烯酸乙酯(AAEM)/聚醚胺交联体系,制备了一种自交联丙烯酸乳胶,研究了不同功能单体、衣康酸、LMA和AAEM/聚醚胺对乳胶及涂膜性能的影响。结果表明:衣康酸用量为3.0%(以单体总质量计,下同)、LMA用量为4.5%、AAEM用量为9.0%、AAEM与聚醚胺物质的量比为2∶1时,制备的单组分水性丙烯酸涂料在PC塑料上具有优异的附着力、耐乙醇擦拭性和耐蒸煮性。In order to overcome the problem of poor performance of waterborne coatings on polycarbonate(PC)plastics.Methyl methacrylate(MMA),styrene(St)and butyl acrylate(BA)were used as the main monomer,itaconic acid as a functional monomer,the introduction of a long-chain alkyl monomer lauryl methacrylate(LMA)and acetoacetoxyethyl methacrylate(AAEM)/polyether amine were cross-linking system,which prepared a self-linked acrylic latex.The effects of functional monomers,itaconic acid,LMA and AAEM/polyether amine on the performance of acrylic latex and coating film were discussed.The experimental results showed that when the itaconic acid was 3.0%of the total monomers,LMA 4.5%,AAEM 9.0%,and AAEM/polyether amine molar ratio was 2∶1,the prepared single-group water-based acrylic coatings presented excellent adhesion,ethanol-resistant and cooking-resistant on the PC plastic.

关 键 词：塑料涂料 丙烯酸乳胶 耐蒸煮性 耐乙醇擦拭性 附着力 

分 类 号：TQ635[化学工程—精细化工]