太阳能直接驱动CH_(4)和CO_(2)干重整技术进展  

Research progress in solar-driven CH_(4) and CO_(2) dry reforming technologies

作　　者：薛耀 李金昊[1] 杨志佳 王若愚 孟宪光 林蒙 赵宇飞 XUE Yao;LI Jinhao;YANG Zhijia;WANG Ruoyu;MENG Xianguang;LIN Meng;ZHAO Yufei(State Key Laboratory of Chemical Resource Engineering,College of Chemistry,Beijing University of Chemical Technology,Beijing 100029,China;Quzhou Institute for Innovation in Resource Chemical Engineering,Quzhou 323000,China;College of Material Science and Engineering,North China University of Science and Technology,Tangshan 063210,China;Southern University of Science and Technology,Energy Institute for Carbon Neutrality,Shenzhen 518055,China)

机构地区：[1]北京化工大学化工资源有效利用国家重点实验室,北京100029 [2]衢州资源化工创新研究院,浙江,衢州323000 [3]华北理工大学材料科学与工程学院,河北唐山063210 [4]南方科技大学碳中和能源研究院,广东深圳518055

出　　处：《洁净煤技术》2024年第4期21-40,共20页Clean Coal Technology

基　　金：国家重点研发计划项目资助(2023YFB4104600)。

摘　　要：随着世界经济的快速发展,能源短缺和环境污染已成为关注焦点,化石燃料的快速消耗使得温室效应持续增强,对全球环境和气候造成了严重影响。利用丰富和清洁的太阳能驱动的方式可以快速靶向供热,在温和条件下将2种主要温室气体(CH_(4)/CO_(2))转化为有价值的合成气,可以大幅降低传统热催化过程所产生的能耗及碳排放。然而,当前太阳能直接驱动干重整制合成气技术距离工业应用仍有一些距离,存在反应分子转化速率低、光能-化学能转化效率低、催化剂易烧结及积碳造成的催化剂失活等问题。针对干重整反应的固有特性以及当前光热研究领域普遍存在的问题,围绕该反应涉及的催化剂制备、载体构筑、反应器及系统搭建与优化,详细介绍了光热干重整反应的研究进展,最后展望了太阳能直接驱动光热催化干重整体系的前景和挑战。With the rapid development of the world economy,energy scarcity and environmental pollution have become focal points of concern.The rapid consumption of fossil fuels has led to the continuous enhancement of the green house effect,causing severe impacts on global environment and climate.Utilizing abundant and clean solar-driven approaches can rapidly target heating supply,converting two major greenhouse gases(CH_(4)/CO_(2))into valuable syngas under mild conditions,thereby significantly reducing the energy consumption and carbon emissions generated by traditional thermocatalytic processes.However,the current solar-driven dry reforming syngas technology still faces several challenges on its path towards industrial application,including low conversion rates of reactant molecules,low efficiency of solar-to-chemical energy conversion,catalyst sintering,and catalyst deactivation caused by carbon deposition.This paper focused on the inherent characteristics of dry reforming reactions and the common issues in the field of solar thermal research,detailing the research progress on photo-thermal dry reforming reactions concerning catalyst preparation,support construction,reactor and system establishment,and optimization.Finally,the prospects and challenges of solar-driven photo-thermal catalytic dry reforming systems were discussed.

关 键 词：CO_(2)干重整 合成气 光热催化 结构载体 太阳能系统 

分 类 号：TQ034[化学工程] TQ426