MOFs及其衍生材料在催化有机反应中的研究进展  

Research progress of MOFs and their derivative materials in catalysis of organic reactions

作　　者：孔治国[1,2] 刘福星 刘星延 冯静东[1,2] KONG Zhi-guo;LIU Fu-xing;LIU Xing-yan;FENG Jing-dong(Key Laboratory of Preparation and Applications of Environmental Friendly Materials of the Ministry of Education,Jilin Normal University,Changchun 130103,China;College of Chemistry,Jilin Normal University,Siping 136000,China)

机构地区：[1]吉林师范大学环境友好材料制备与应用教育部重点实验室,吉林长春130103 [2]吉林师范大学化学学院,吉林四平136000

出　　处：《吉林师范大学学报（自然科学版）》2024年第2期23-31,共9页Journal of Jilin Normal University:Natural Science Edition

基　　金：吉林省科技发展计划项目(20240101148JC);四平市科技发展计划项目(2016048)。

摘　　要：金属有机框架材料(MOFs)是金属离子或团簇和有机配体通过配位键结合而形成的周期性重复的多孔晶体材料,有机配体一般带有羧基、膦酸基、吡唑基、咪唑基等.经过几十年的发展,MOFs的数量迅速增长,因其有着十分丰富的拓扑结构和独特的物理和化学性质,被广泛应用于气体吸附、生物制药、工业催化、能源存储和分子分离等领域.本文主要介绍MOFs催化剂在有机反应中应用的最新进展,包括氧化反应、还原反应、偶联反应、缩合反应和不对称反应.Metal-organic frameworks(MOFs)are periodic,repetitive and porous crystal materials formed by the combination of metal ions or clusters and organic ligands through coordination bonds.The organic ligands generally have carboxyl groups,phosphonate groups,pyrazole groups and imidazole groups,etc.After decades of development,the number of discovered MOFs has rapidly increased,and they have very rich topological structures and unique physical and chemical properties.Therefore,they are widely used in gas adsorption,biomedicine,industrial catalysis,energy storage,and molecular separation.This article mainly introduces the latest progress of the application of MOFs catalysts in organic reactions,including oxidation reactions,reduction reactions,coupling reactions,condensation reactions and asymmetric reactions.

关 键 词：金属有机框架材料 催化剂 有机合成 

分 类 号：TB333[一般工业技术—材料科学与工程]