镍-钴硫/磷化物纳米复合材料用于析氢反应  

Nickel⁃Cobalt sulfide/phosphide nanocomposite for hydrogen evolution reaction

作　　者：魏素凤 孙殿东 张君宇 王瑜喆 李恩泽 王国勇[3] WEI Su-feng;SUN Dian-dong;ZHANG Jun-yu;WANG Yu-zhe;LI En-ze;WANG Guo-yong(College of Materials Science and Engineering,Changchun University of Technology,Changchun 130012,China;State Key Laboratory of Metal Material for Marine Equipment and Application,Ansteel Group,Anshan 114021,China;College of Materials Science and Engineering,Jilin University,Changchun 130022,China)

机构地区：[1]长春工业大学材料科学与工程学院,长春130012 [2]鞍钢集团海洋装备用金属材料及其应用国家重点实验室,辽宁鞍山114021 [3]吉林大学材料科学与工程学院,长春130022

出　　处：《吉林大学学报（工学版）》2024年第3期674-682,共9页Journal of Jilin University:Engineering and Technology Edition

基　　金：国家自然科学基金重点研发项目(2018YFA0702304).

摘　　要：为寻求廉价、性能优异且反应稳定的碱性析氢催化剂以代替贵金属,以过渡金属Ni、Co为研究对象,通过一步煅烧处理得到Ni-Co硫/磷化物催化剂,借助X射线检测和能谱分析等方法验证了催化剂的成功制备。电化学测试结果表明,由于阴/阳离子之间的协同作用,所制备的Ni-Co硫/磷化物的催化活性和电荷转移速率均超过Ni-Co氢氧化物/硫化物/磷化物。Ni-Co硫/磷化物仅需要106 mV的过电势就可以达到10 mA·cm^(−2)的电流密度,循环寿命超过20 h。For seeking cheap,high performance and stable catalysts to replace noble metals.In this paper,sulfide/phosphide catalysts were obtained by one-step annealing treatment with transition metals Ni/Co,and the successful preparation of the catalysts was verified by electron detection and elemental analysis method.The electrochemical test results showed that the catalytic activity and charge transfer rate of the prepared Ni-Co sulfide/phosphide exceeded those of Ni-Co hydroxide/sulfide/phosphide due to the synergistic effect between anions/cations.Ni-Co sulfur/phosphide only requires an overpotential of 106 mV to achieve a current density of 10 mA·cm^(-2) and the stability was more than 20 h.

关 键 词：过渡金属催化剂 析氢反应 硫磷化物 异质结构 协同作用 

分 类 号：TB332[一般工业技术—材料科学与工程]