赛克季戊四醇混合改性树脂的制备及性能  

Preparation and Performance of Resin Modified with a Mixture of THEIC and Pentaerythritol

作　　者：郭秀安 赵震 李浩然 唐林生[3] Guo Xiuan;Zhao Zhen;Li Haoran;Tang Linsheng(Shandong Brothers Technology Co.,Ltd.,Weifang,Shandong,262715;Shandong Engineering Laboratory of Environment-friendly Macromolecular Flame Retardant Material,Weifang,Shandong,262715;College of Chemical Engineering,Qingdao University of Science and Technology,Qingdao,Shandong,266042)

机构地区：[1]山东兄弟科技股份有限公司,山东潍坊262715 [2]山东省环境友好大分子阻燃材料工程实验室,山东潍坊262715 [3]青岛科技大学化工学院,山东青岛266042

出　　处：《现代塑料加工应用》2024年第2期25-28,共4页Modern Plastics Processing and Applications

基　　金：国家自然科学基金(21878165)。

摘　　要：以六羟甲基三聚氰胺(HMM)、赛克和季戊四醇(PER)为原料,磷酸为催化剂,通过干法醚化和缩聚合成了一种新型的赛克季戊四醇混合改性树脂成炭剂。结果表明:该混合改性树脂的热稳定性和对聚丙烯(PP)的阻燃性能介于PER改性树脂和赛克改性树脂之间,但混合改性明显改善了阻燃材料的颜色。赛克和PER的物质的量比对混合改性树脂的热稳定性、阻燃性能及阻燃材料的颜色有影响,赛克与PER最合适的物质的量比为1.3∶1.0。Using hexamethylene-melamine(HMM),THEIC and pentaerythritol(PER)as raw materials and phosphoric acid as catalyst,a new type charring agent of resin modified with a mixture of THEIC and PER was synthesized by dry etherification and polycondensation.The results show that the thermal stability and flame retardancy of the modified resin on PP were between those of the PER modified resin and the THEIC modified resin,but the color of the modified resin is improved significantly.The heat stability,flame retardant property and color of flame retardant materials are affected by the molar ratio of THEIC and PER.The optimum molar ratio of THEIC and PER is 1.3∶1.0.

关 键 词：赛克季戊四醇混合改性树脂 成炭剂 热稳定性 阻燃作用 

分 类 号：TQ325[化学工程—合成树脂塑料工业]