柠檬酸-氯化锌协同酸解分离废旧涤棉混纺织物  

Separation of Waste Polyester/Cotton Blended Fabrics Using Synergistic Acidolysis of Citric Acid and Zinc Chloride

作　　者：王庭丽 孙娟娟 史肖蓉 王潮霞 WANG Ting-li;SUN Juan-juan;SHI Xiao-rong;WANG Chao-xia(College of Textile Science and Engineering,Jiangnan University,Wuxi 214122,China)

机构地区：[1]江南大学纺织科学与工程学院,无锡214122

出　　处：《高分子通报》2024年第5期666-674,共9页Polymer Bulletin

基　　金：国家自然科学基金(基金号21975107)。

摘　　要：针对废旧涤棉织物的大量存在,且回收困难、混合再利用产物附加值低下等问题,利用柠檬酸和氯化锌酸解棉纤维,并探讨了分离的机理。当柠檬酸浓度为30%,氯化锌浓度为35%,温度为90℃,时间为3 h达到涤棉分离目的。纤维素回收率为84.1%,且依然保持纤维素I型的晶体结构,聚合度和结晶度分别下降了83.8%和27.3%。涤纶回收率为97.8%,在分离处理后几乎没有损伤。柠檬酸和氯化锌酸解体系可循环利用多次,实现了废旧涤棉混纺织物的分离回收。The recycling process of waste polyester/cotton fabrics presents an enormous challenge due to a considerable quantity of waste,the intricate methodology and the minimal value of reused mixed products.The synergistic effect of citric acid and zinc chloride is utilized to effectively break cotton fibers while investigating the underlying mechanism of separation.By employing a concentration of 30%citric acid,35%zinc chloride,a temperature of 90°C,and 3 h,successful separation between polyester and cotton is achieved.The recovery rate of cellulose attains 84.1%,while retaining its crystalline structure characteristic of cellulose I.However,the degree of polymerization and crystallinity experience a decrease of 83.8%and 27.3%,respectively.Polyester fibers demonstrate a remarkable recovery rate of 97.8%,remaining largely undamaged throughout the separation process.The citric acid and zinc chloride acidolysis system can be recycled several times,enabling the separation and recovery of waste polyester/cotton blended fabrics.

关 键 词：废旧涤棉织物 分离 纤维素 柠檬酸 氯化锌 

分 类 号：X705[环境科学与工程—环境工程] TQ028[化学工程]