Tuning interfacial charge transfer for efficient visible-light-driven photodegradation and simultaneous H_(2)evolution  

作　　者：Zhiyang Li Yaogang Chen Yinghe Zhang Wei Ai Qian Lei Tingjun Yao Dan Zhong Wenjie Liu Wenbiao Jin Lei Yang 

机构地区：[1]State Key Laboratory of Urban Water Resource and Environment,Shenzhen Key Laboratory of Organic Pollution Prevention and Control,School of Civil and Environmental Engineering,Harbin Institute of Technology Shenzhen,Shenzhen 518055,China [2]Key Laboratory of Northwest Water Resources,Environment and Ecology,Ministry of Education,School of Environmental and Municipal Engineering,Xi’an University of Architecture and Technology,Xi’an 710055,China [3]CNAS Accredited Test Center,Guangdong Engineering Technology Research Center of Air Purification,Healthlead Co.,Ltd.,Shenzhen 518055,China [4]School of Science,Harbin Institute of Technology Shenzhen,Shenzhen 518055,China

出　　处：《Journal of Materials Science & Technology》2024年第1期35-49,共15页材料科学技术（英文版）

基　　金：supported by the Natural Science Foundation of Shenzhen(No.GXWD20201230155427003-20200802110025006);the National Natural Science Foundation of China(Nos.52170157 and 52111530188);the Major Program of Jiangxi Provincial Depart-ment of Science and Technology(No.2022KSG01004);the Natural Science Foundation of Shenzhen(No.JCYJ20220531095408020);the Start-up Grant Harbin Institute of Technology(Shenzhen)(No.IA45001007);the Start-up Talent Grant at Harbin Institute of Technology(Shenzhen)(No.HA11409066).

摘　　要：The edge-graphitized carbon nitride(C_(3)N_(4)-C g)was prepared by secondary pyrolysis to construct ZnO/C_(3)N_(4)-C g(ZCN)type-Ⅱheterojunction photocatalyst via a facile sonication dispersion method,which achieved∼7.04-fold and∼18.3-fold enhanced visible-light-driven photocatalytic performance for refrac-tory micropollutant removal and simultaneous hydrogen(H_(2))evolution respectively compared to con-ventional ZnO/g-C_(3)N_(4)Step-scheme heterojunction.The apparent quantum efficiency of the ZCN_(0.4)het-erojunction reaches 0.92%(λ=420 nm).Such excellent performance stems from that the edge-graphene moieties stitched onto the interface of heterojunction extend light absorption to the full visible spec-trum,meanwhile,the built-in electric field generated during Fermi level alignment accompanying fa-vorable band-bending structure provides an effective pathway for the rapid migration of photoinduced electrons via the edge graphene channel to improve interfacial charge separation efficiency.Interestingly,the midgap states introduced in ZCN heterojunction could temporarily retain photoexcited electrons to effectively inhibit the in situ carrier recombination for improved photocatalytic H_(2)evolution.Moreover,ZCN/peroxymonosulfate system exhibited excellent anti-interference performance against complex water bodies under visible illumination due to the synergistic effect between the co-existing anions and organic matter.Meanwhile,the eco-friendly nature of the ZCN/peroxymonosulfate system showed no biotoxicity of reaction filtrate on cell proliferation after treatment,which avoided secondary contamination.Consid-ering the outstanding performance in photocatalysis,the ZCN system exhibits broad potential for practical applications in water pollution control and green energy production.

关 键 词：ZnO C_(3)N_(4)-C g HETEROJUNCTION PHOTODEGRADATION Hydrogen evolution 

分 类 号：O64[理学—物理化学]