高固含低黏度生物基氟碳树脂的合成及性能  

Synthesis and properties of biobased fluorocarbon resin with high solid content and low viscosity

作　　者：周丽莎 安桂磊 黄百涛 吴英魁 陈博涵 齐文 ZHOU Lisha;AN Guilei;HUANG Baitao;WU Yingkui;CHEN Bohan;QI Wen(School of Chemistry and Chemical Engineering,Guangxi Minzu University,Key Laboratory of Chemistry and Engineering of Forest Products,State Ethnic Affairs Commission,Guangxi Key Laboratory of Chemistry and Engineering of Forest Products,Guangxi Collaborative Innovation Center for Chemistry and Engineering of Forest Products,Nanning 530006,Guangxi,China;Dalian University of Technology,Dalian 116012,Liaoning,China)

机构地区：[1]广西民族大学化学化工学院、林产化学与工程国家民委重点实验室、广西林产化学与工程重点实验室/协同创新中心,广西南宁530006 [2]大连理工大学,辽宁大连116012

出　　处：《精细化工》2024年第5期1143-1151,共9页Fine Chemicals

基　　金：广西科技厅广西科技基地和人才专项(桂科AD20297016);广西高等学校千名中青年骨干教师培育计划项目;广西民族大学2019年引进人才科研启动项目(2019KJQD11);广西自然科学基金面上项目(桂科2021JJA160107)。

摘　　要：将生物基原料氢化松香醇与三乙胺、对羟基苯甲醚、丙烯酰氯反应制备了可聚合的丙烯酸氢化松香醇酯,然后其与一系列丙烯酸及其衍生物通过共聚,制备了高固含低黏度生物基氟碳树脂。结合分子动力学模拟,分析了丙烯酸氢化松香醇酯降黏机理,探究了生物基氟碳树脂成膜后的涂膜性能。结果表明,随着丙烯酸氢化松香醇酯质量分数的增加,改性氟碳树脂运动黏度降低;当丙烯酸氢化松香醇酯质量分数为18.6%时,改性氟碳树脂固含量为78.56%,其运动黏度与石油树脂叔碳酸乙烯酯改性氟碳树脂相当,远低于不含大体积侧基的改性氟碳树脂;与叔碳酸乙烯酯相比,丙烯酸氢化松香醇酯的空间体积更大,侧基体积效应更明显,分子间作用力小,降黏效果好;丙烯酸氢化松香醇酯改性氟碳涂膜硬度、附着力高于叔碳酸乙烯酯改性氟碳涂膜,耐化学腐蚀性略低于叔碳酸乙烯酯改性氟碳涂膜。Polymerizable hydroabietyl acrylate was prepared from the reaction of biomass raw material hydrogenated rosinol with triethylamine,p-hydroxyanisole and acryloyl chloride,and then copolymerized with a series of acrylates and their derivatives to obtain a bio-based fluorocarbon resin with high solid content and low viscosity.The viscosity reduction mechanism of hydroabietyl acrylate was analyzed by molecular dynamics simulation method.And the coating performance of bio-based fluorocarbon resin was further explored.The results indicated that the kinematic viscosity of modified fluorocarbon resin decreased with the increase of the mass fraction of hydroabietyl acrylate.When the mass fraction of hydroabietyl acrylate was 18.6%,the solid content of modified fluorocarbon resin was 78.56%,with its kinematic viscosity equivalent to that of fluorocarbon resin modified by vinyl neodecanoate but far lower than that of modified fluorocarbon resin without large volume side groups.Compared with petroleum resin vinyl neodecanoate,hydroabietyl acrylate exhibited larger space volume,more obvious side group volume effect,lower intermolecular interaction force and lower viscosity.In comparison to that modified by vinyl neodecanoate,fluorocarbon coating modified by hydroabietyl acrylate displayed higher hardness and adhesion,and slightly lower chemical corrosion resistance.

关 键 词：生物基氟碳树脂 防腐涂料 高固含量 氢化松香 丙烯酸系列化学品 

分 类 号：TQ630.43[化学工程—精细化工] TQ320.1