黑磷半导体光物理及应用研究进展  

Advancements in photophysics research and applications of phosphorene semiconductors

作　　者：黄卫春 訾由 王梦可 胡兰萍[1] 王云征 谢中建[3] 仇萌[4] 张晗[3] HUANG Weichun;ZI You;WANG Mengke;HU Lanping;WANG Yunzheng;XIE Zhongjian;QIU Meng;ZHANG Han(School of Chemistry and Chemical Engineering,Nantong University,Nantong 226019,Jiangsu Province,P.R.China;Center for Optics Research and Engineering,Key Laboratory of Laser and Infrared System of Ministry of Education,Shandong University,Qingdao 266237,Shandong Province,P.R.China;Shenzhen Engineering Laboratory of Phosphorene and Optoelectronics International Collaborative Laboratory of 2D Materials,College of Optoelectronic Engineering,Shenzhen University,Shenzhen 518060,Guangdong Province,P.R.China;Key Laboratory of Marine Chemistry Theory and Technology of Ministry of Education,Ocean University of China,Qingdao 266100,Shandong Province,P.R.China)

机构地区：[1]南通大学化学化工学院,江苏南通226019 [2]山东大学光学高等研究中心,激光与红外系统教育部重点实验室,山东青岛266237 [3]深圳市黑磷工程实验室与二维材料光电国际合作联合实验室,深圳大学物理与光电工程学院,广东深圳518060 [4]中国海洋大学海洋化学理论与工程技术教育部重点实验室,山东青岛266100

出　　处：《深圳大学学报（理工版）》2024年第3期323-347,共25页Journal of Shenzhen University(Science and Engineering)

基　　金：国家自然科学基金资助项目(61805147,52103316)。

摘　　要：与其他二维材料相比,二维黑磷具有较高的载流子迁移率、宽可调带隙和面内各向异性等特点,在晶体管、光子学、光电子学、传感器、电池和催化等领域引起科学家的广泛关注.然而,黑磷在自然环境条件下的不稳定性以及大面积、高质量半导体黑磷纳米材料制备的局限性严重滞缓了其在纳米器件、催化以及生物光子学领域的快速发展.本工作总结了近年来高稳定性黑磷纳米材料的可控制备和光学性质,重点突出其在光电探测器、非线性和线性光学、光催化和生物光子学等光学应用方面的研究进展,并对黑磷在未来光电子器件、光催化以及生物光子的挑战及机遇做出相应展望.Compared with other two-dimensional materials,two-dimensional black phosphorus(BP)has attracted extensive attention across various fields including transistors,photonics,optoelectronics,sensors,batteries and catalysis in recent years owing to its high carrier mobility,wide adjustable band gap,and in-plane anisotropy.However,the instability of black phosphorus in natural environmental conditions and the chanllenges in the fabrication of large-area,high-quality semiconducting black phosphorus nanostructures seriously have hampered its rapid development in the field of nanodevices,catalysis and biophotonics.In this work,we summarize the controlled fabrication and optical properties of highly stable BP nanostructures in recent years.The research advances in photoresponse applications,including photodetectors,nonlinear and linear photonics,photocatalysis and biophotonics,are highlighted.Additionally,the challenges and opportunities of BP nanostructures in future optoelectronic devices,photocatalysis and biophotonics are discussed.

关 键 词：生物光子学 二维材料 磷烯 半导体 光学性质 光电探测 非线性光学 医学应用 

分 类 号：Q437[生物学—生理学] Q632