Multiscale microstructural consideration of enhanced shear strength in TiAl intermetallic/K4169 alloy composite joints prepared by vacuum brazing with(Ti,Zr)-Ni-based amorphous filler metal  

作　　者：Liangliang Zhang Honggang Dong Peng Li Baosheng Wu Yueting Ma Libing Huang Chao Li Jiachen Li 

机构地区：[1]School of Materials Science and Engineering,Dalian University of Technology,Dalian 116024,China

出　　处：《Journal of Materials Science & Technology》2024年第5期51-70,共20页材料科学技术（英文版）

基　　金：supported by the National Natural Science Foundation of China(Nos.52275314 and 52075074).

摘　　要：TiAl intermetallic could be used to replace Ni-based alloy in assemblies to generate excellent specific strength.A(Ti,Zr)-Ni-based amorphous filler metal Ti_(21.25)Zr_(25)Ni_(25)Cu_(18.75)(at.%)was designed using a cluster-plus-glue-atom model to successfully vacuum braze K4169 and TiAl bimetallic assemblies.At various brazing temperatures and holding time,the quantitative relationships between lattice distortion,grain boundary,dislocation density,and hardness,elastic modulus,shear strength of the joints were investigated.Meanwhile,the fracture mechanism of the joints was revealed.The brazed seam mainly consisted of solid diffusion reaction layers(ZonesⅠandⅢ)and filler metal residue zone(ZoneⅡ).When the brazing temperature increased to 1030℃,grain refinement occurred in the brazed seam.ZoneⅠwas primarily composed of(Ni)ss[0-11]+TiNi[011]/(Cr,Fe,Ni)ss[0-11]/(Ti,Zr)Ni[0-1-1]+(Cr,Fe,Ni)ss[0-11].The(Ti,Zr)(Ni,Cu)[001]and(Ti,Zr)(Ni,Cu)[101]intermetallic compound-based solid solutions were formed in ZoneⅡ.And the lattice distortion of(Ti,Zr)(Ni,Cu)[101]and(Ti,Zr)(Ni,Cu)[001]was 32.05%and 14.82%,respectively.As a result,the proportion of low angle grain boundaries(LAGBs)and deformed grains in ZoneⅡrose to 38.6%and 38.7%.In ZonesⅠandⅢ,the proportion of LAGBs reduced to 8%and 3.4%,respectively.As the holding time increased,the long-range diffusion of Al in ZoneⅡcaused the(Ti,Zr)(Ni,Cu)[001]with cubic structure to transform into(Ti,Zr)(Ni,Cu,Al)[00-1]with hexagonal crystal system structure,where the lattice distortion was 4.42%and 10.49%for a and c.At 1030℃/10 min,the average geometrically nec-essary dislocation densities(GNDs)in ZonesⅠ,ⅡandⅢwere 9.87×10^(14)m^(-2),8.55×10^(14)m^(-2)and 11.4×10^(14)m^(-2),respectively.Therefore,the shear strength of joints reached 322 MPa due to the lattice distortion,dislocation strengthening and fine grain strengthening.Meanwhile,the plastic and brittle hard phases were generated in ZoneⅡand displayed a mechanical interlocking structure that contributed t

关 键 词：K4169/Ti_(21.25)Zr_(25)Ni_(25)Cu_(18.75)/TiAl composite joints Intermetallic compound-based solid solution Lattice distortion Elastic modulus 

分 类 号：TG1[金属学及工艺—金属学]