微弧氧化后Mg-8Li合金表面MgLiAlY-LDHs@GO膜层的生长及耐蚀性能  

Growth Behavior and Corrosion Resistance of MgLiAlY-LDHs@GO on Mg-8Li Alloy after Micro Arc Oxidation

作　　者：周岩 吴量[1,2] 汪安 汪瑞俊 姚文辉 袁媛 谢治辉[4] 张欣怡 吴嘉豪[1,2] 陈勇花 潘复生 ZHOU Yan;WU Liang;WANG An;WANG Ruijun;YAO Wenhui;YUAN Yuan;XIE Zhihui;ZHANG Xinyi;WU Jiahao;CHEN Yonghua;PAN Fusheng(Chongqing University,Chongqing 400044,China;National Engineering Research Center for Magnesium Alloys,Chongqing 400044,China;Chizhou Research Institute of Quality Supervision and Inspection,Anhui Chizhou 247100,China;China West Normal University,Sichuan Nanchong 637002,China)

机构地区：[1]重庆大学,重庆400044 [2]国家镁合金工程研究中心,重庆400044 [3]池州市质量监督检验研究院,安徽池州247100 [4]西华师范大学,四川南充637002

出　　处：《表面技术》2024年第9期22-33,74,共13页Surface Technology

基　　金：国家自然科学基金(52171101)。

摘　　要：目的提高Mg-8Li合金的耐蚀性能。方法首先在Mg-8Li合金表面制备微弧氧化膜(MAO),然后使用原位水热法在微弧氧化膜表面原位生长掺杂氧化石墨烯(GO)的四元(MgLiAlY)层状双羟基金属氧化物(LDHs)智能自修复膜层。采用SEM、XRD、FT-IR、EDS、ICP等手段研究MgLiAlY-LDHs@GO膜层的形貌、结构以及成分。通过EIS、Tafel以及浸泡试验等研究膜层的耐蚀性能,分析膜层的腐蚀行为,阐释其耐蚀机理。结果GO的掺杂可以促使LDHs纳米片生长得更加致密,主体层板中具有缓蚀作用的Y3+可以提高涂层的耐蚀性,四元LDHs的生长所需要的Mg^(2+)、Li^(+)、Al^(3+)等离子来源于镁锂合金基体以及微弧氧化膜的溶解,其中Li+也可以促进LDHs纳米片生长得更为均匀细密。膜层的腐蚀电流密度为6.03×10^(–7)A/cm^(2),比MAO膜层降低了1个数量级,提高了镁锂合金的耐蚀性能。结论GO的负载使LDHs的耐蚀性能和膜层稳定性均有一定程度的提升,引入稀土元素Y会改变LDHs的骨架,造成晶格畸变,使得LDHs微观形貌呈现褶皱状,剩下部分以Y(OH)3形式存在于涂层表面,可进一步提高膜层的耐蚀性能和稳定性。Magnesium-lithium alloy is currently the world's lightest metal structural material,with high specific strength,high specific stiffness,good seismic performance and many other advantages,and has a good prospect in aerospace,digital communications,new energy and other fields.However,the electrode potential of magnesium-lithium alloys is low,resulting in poor corrosion resistance,so its application development has been seriously affected.Currently,the enhancement of the corrosion resistance of magnesium and lithium alloys can be divided into two methods:heat treatment and deformation processing through the alloy from the alloy alloying,or the magnesium and lithium alloys prepared on the surface of the protective coating.These methods can only play a passive corrosion-resistant effect because the damage may be caused immediately or the failure may be formed gradually.Self-healing coatings are now gradually attracting attention,compared with the above methods and it can realize the effect of active corrosion resistance,so the self-healing coatings to LDHs coating become more prominent.The micro arc oxidation(MAO)was carried out on the surface of Mg-8Li alloy at first,and then a quaternary(MgLiAlY)layered double hydroxides(LDHs)smart self-repairing coating doped with graphene oxide(GO)was grown on the surface after the micro arc oxidation in-situ by hydrothermal method.The morphology,structure,and composition of the MgLiAlY@GO coating were investigated by SEM,XRD,FT-IR,EDS,and ICP.The corrosion resistance of the coating was investigated by EIS,Tafel and immersion tests.The corrosion behavior of the coating was analyzed and the corrosion resistance mechanism was elucidated.The doping of GO could promote the growth of LDHs nanosheets to become denser.Y3+,which had a corrosion inhibiting effect on the main layer plate,could improve the corrosion resistance of the coating.The Mg^(2+),Li^(+),and Al^(3+) required for the growth of quaternary LDHs came from the dissolution of magnesium lithium alloy matrix and micro arc oxid

关 键 词：镁锂合金 微弧氧化 层状双羟基金属氧化物 氧化石墨烯 耐蚀性能 自修复膜层 

分 类 号：TG174.4[金属学及工艺—金属表面处理]