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作 者:Lu-Jie Li Yuli He Yunhui Yang Jun Guo Zhan Lu Congyang Wang Shaolin Zhu Shou-Fei Zhu
机构地区:[1]College of Chemistry,Nankai University,Tianjin 300071 [2]School of Chemistry and Chemical Engineering,Nanjing University,Nanjing,Jiangsu Province 210093 [3]Institute of Chemistry,Chinese Academy of Sciences and University of Chinese Academy of Sciences,Beijing 100190 [4]Department of Chemistry,Zhejiang University,Hangzhou,Zhejiang Province 310058
出 处:《CCS Chemistry》2024年第3期537-584,共48页中国化学会会刊(英文)
基 金:the National Key R&D Program of China(grant no.2021YFA1500200);the National Natural Science Foundation of China(grant nos.92256301,22221002,22025109,21831008,22101286,and 22271249);the Fundamental Research Funds for the Central Universities(grant nos.226-2022-00224 and 226-2023-00115)for financial support.
摘 要:This paper reviewed the recent research progress of organic reactions catalyzed by four typical earthabundant and 3d metal catalysts:Mn,Fe,Co,and Ni complexes and mainly focused on the reactions in which these 3d metal catalysts exhibited obvious advantages over other catalysts.The mechanism that makes these 3d metal catalysts show unusual properties is another focus of this paper.An outlook on 3d metal complexes-catalyzed organic reactions was also considered.
关 键 词:Earth-abundant metal catalysts sustainable organic synthesis structure-function relationships organometallic intermediates hydrocarbon transformations
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