羧酸类金属配合物的研究进展  

Progress in the study of carboxylic acid metal complexes

作　　者：张丽 罗梅 ZHANG Li;LUO Mei(School of Chemistry and Chemical Engineering,Hefei University of Technology,Hefei 230009,Anhui,China)

机构地区：[1]合肥工业大学化学与化工学院,安徽合肥230009

出　　处：《化学研究》2024年第3期253-262,共10页Chemical Research

基　　金：横向联合基金项目(W2022JSKF0585)。

摘　　要：以有机羧酸分子为配体,金属阳离子为中心合成的配合物被称为羧酸类金属配合物。有机羧酸作为一类重要的配体,因具有单齿配位、二齿螯合、可同时桥连多个金属离子及其他多种配位模式,在构建金属-有机配合物方面有着广阔的应用前景。有机羧酸配体种类繁多,与金属反应形成配合物的形式也多种多样。因此,介绍了羧酸类金属配合物的合成方法,探讨了各种有机羧酸配体所形成的金属配合物及其研究进展,同时对羧酸类金属配合物的未来发展进行了前瞻性的展望。The complexes involving organic carboxylic acid molecules as ligands and metal cations as centers are called carboxylic acid metal complexes.As an important class of ligands,organic carboxylic acids,have been widely used in constructing organometallic complexes accordingly due to their monodentate coordination,bidentate chelation,ability to simultaneously bridge multiple metal ions,and various other coordination modes.Based on this,the synthetic methods of carboxylic acid metal complexes are introduced,and the formation from various organic carboxylic acid ligands and their research progress are also discussed.At the same time,the future development of carboxylic acid metal complexes is also prospected.

关 键 词：羧酸类金属配合物 配合物的合成方法 羧酸配体 研究进展 

分 类 号：O614[理学—无机化学]