光电联合催化烯烃自由基环合反应的研究进展  

Advances in Electrophotocatalytic Radical Cyclization of Alkenes

作　　者：王冬寅 梁德强 Wang Dongyin;Liang Deqiang(School of Chemistry and Chemical Engineering,Kunming University,Kunming 650214,China;Key Laboratory of Metal Organic Molecular Materials and Devices in Yunnan Province,Kunming 650214,China)

机构地区：[1]昆明学院化学化工学院,云南昆明650214 [2]云南省金属有机分子材料与器件重点实验室,云南昆明650214

出　　处：《云南化工》2024年第5期1-6,共6页Yunnan Chemical Technology

基　　金：国家自然科学基金项目(22061024);云南省兴滇英才青年人才专项(YNWR-QNBJ-2018-133);云南贵金属实验室基础研究项目(YPML-2023050262);昆明学院科学研究项目(XPZJ2204)。

摘　　要：烯烃是重要的化工原料,可以制备药物、农药和涂料等高价值化学品。随着光催化和电催化氧化还原反应研究的发展,开发了将二者结合解决光/电各自局限性的光电联合催化技术。通过文献研究,根据3种不同自由基的产生方式,综述了光电联合催化烯烃自由基环合反应的研究进展。Alkenes are fundamental feedstocks for chemical industries,and they can be used to prepared value-added chemicals such as pharmaceuticals,pesticides and coatings.With the development of photocatalysis and electroredox reactions,the electrophotocatalytic technology has been developed by merging the two technologies to address their limitations.Based on the literature review,the advances in electrophotocatalytic radical cyclization of alkenes in the light of radical generation mode was reviewed according to three different free radical generation modes.

关 键 词：光电联合催化 自由基反应 烯烃 环合反应 

分 类 号：O621.3[理学—有机化学]