Reversible solid-liquid conversion enabled by self-capture effect for stable non-flow zinc-bromine batteries  

作　　者：Xixi Zhang Xiaoke Wang Guangmeng Qu Tairan Wang Xiliang Zhao Jun Fan Cuiping Han Xijin Xu Chunyi Zhi Hongfei Li 

机构地区：[1]School of Physics and Technology,University of Jinan,Shandong,250022,China [2]Songshan Lake Materials Laboratory,Dongguan,Guangdong,523808,China [3]Department of Materials Science and Engineering,City University of Hong Kong,83 Tat Chee Avenue,Hong Kong,China [4]Faculty of Materials Science and Engineering and Low Dimensional Energy Materials Research Center,Shenzhen Institute of Advanced Technology,Chinese Academy of Sciences,Shenzhen,Guangdong,518055,China [5]School of System Design and Intelligent Manufacturing,Southern University of Science and Technology,Shenzhen,Guangdong,518055,China

出　　处：《Green Energy & Environment》2024年第6期1035-1044,共10页绿色能源与环境（英文版）

基　　金：the Guangdong Basic and Applied Basic Research Foundation(grant number:2019A1515011819,2021B1515120004);National Natural Science Foundation of China(22005207);Open Research Fund of Songshan Lake Materials Laboratory(2021SLABFN04).

摘　　要：Non-flow aqueous zinc-bromine batteries without auxiliary components(e.g.,pumps,pipes,storage tanks)and ion-selective membranes represent a cost-effective and promising technology for large-scale energy storage.Unfortunately,they generally suffer from serious diffusion and shuttle of polybromide(Br^(-),Br^(3-))due to the weak physical adsorption between soluble polybromide and host carbon materials,which results in low energy efficiency and poor cycling stability.Here,we develop a novel self-capture organic bromine material(1,10-bis[3-(trimethylammonio)propyl]-4,4'-bipyridinium bromine,NVBr4)to successfully realize reversible solid complexation of bromide components for stable non-flow zinc-bromine battery applications.The quaternary ammonium groups(NV^(4+)ions)can effectively capture the soluble polybromide species based on strong chemical interaction and realize reversible solid complexation confined within the porous electrodes,which transforms the conventional“liquid-liquid”conversion of soluble bromide components into“liquid-solid”model and effectively suppresses the shuttle effect.Thereby,the developed non-flow zinc-bromide battery provides an outstanding voltage platform at 1.7 V with a notable specific capacity of 325 mAh g^(-1)NVBr4(1 A g^(-1)),excellent rate capability(200 mAh g^(-1)NVBr4 at 20 A g^(-1)),outstanding energy density of 469.6 Wh kg^(-1)and super-stable cycle life(20,000 cycles with 100%Coulombic efficiency),which outperforms most of reported zinc-halogen batteries.Further mechanism analysis and DFT calculations demonstrate that the chemical interaction of quaternary ammonium groups and bromide species is the main reason for suppressing the shuttle effect.The developed strategy can be extended to other halogen batteries to obtain stable charge storage.

关 键 词：Solid-liquid conversion Self-capture Non-flow zinc-bromine batteries Quaternary ammonium 

分 类 号：TM912[电气工程—电力电子与电力传动]