基于不同背景选取方式四极质谱仪数据库匹配分析  

Quadrupole mass spectrometer database identification analysis based on different background selection methods

作　　者：于佳佳 沈辉 王玉涵 罗勇 唐朝阳 YU Jiajia;SHEN Hui;WANG Yuhan;LUO Yong;TANG Chaoyang(Shanghai Yuda Industrial Co.,Ltd.,Shanghai 200240,China;Shanghai Institute of Spacecraft Equipment,Shanghai 200240,China)

机构地区：[1]上海裕达实业有限公司,上海200240 [2]上海卫星装备研究所,上海200240

出　　处：《分析试验室》2024年第5期726-730,共5页Chinese Journal of Analysis Laboratory

摘　　要：电解液测试属于锂电池研究的重点方向之一。质谱法在线测试电解液时,背景信号对搜库结果匹配度有明显的影响。研究了在不同背景选取方式下四极质谱仪识别电解液谱峰的匹配度,结果表明,基于进样阶段选取背景的扣除方法,可更有效地去除环境空气对搜库的干扰,获得更高的搜库匹配度。实验结果为锂电池电解液溶剂原位测试与谱库匹配数据处理提供了科学依据,为复杂环境现场测试的数据处理方法提供了思路。Electrolyte analysis is one of the key directions of lithium ion battery research.When testing the electrolyte online by mass spectrometry,the background signal has a significant effect on the matching degree of the sprectrum identification.The matching degree of electrolyte sprectrum identified by quadrupole mass spectrometer upon different background selection methods was studied.The results showed that the deduction method based on the background selection in the injection stage can more effectively remove the interference of ambient air on the spectrum identification and obtain a higher matching degree.The experimental results provide a scientific basis for the in-situ test and spectrum identification of electrolyte,and ideas for the data processing method of complex environments testing.

关 键 词：锂电池 背景扣除 谱图检索 质谱仪 

分 类 号：O657.63[理学—分析化学]