Deep eutectic solvents:Green multi-task agents for sustainable super green hydrogen technologies  

作　　者：Raiyan Al-Farsi Maan Hayyan 

机构地区：[1]Renewable Energy Engineering Program,Faculty of Engineering and Technology,Muscat University,Muscat 130,Oman [2]Chemical Engineering Program,Faculty of Engineering and Technology,Muscat University,Muscat 130,Oman

出　　处：《Journal of Energy Chemistry》2024年第5期357-382,共26页能源化学（英文版）

基　　金：the Ministry of Higher Education,Research and Innovation(MoHERI)Oman for their support of this research through TRC block funding Grant no.:BFP/RGP/EBR/22/378。

摘　　要：While reliance on renewable energy resources has become a reality, there is still a need to deploy greener and more sustainable methods in order to achieve sustainable development goals. Indeed, green hydrogen is currently believed to be a reliable solution for global warming and the pollution challenges arising from fossil fuels, making it the resilient fuel of the future. However, the sustainability of green hydrogen technologies is yet to be achieved. In this context, generation of green hydrogen with the aid of deep eutectic solvents(DESs) as green mixtures has been demonstrated as a promising research area. This systematic review article covers green hydrogen generation through water splitting and biomass fermentation when DESs are utilized within the generation process. It also discusses the incorporation of DESs in fuel cell technologies. DESs can play a variety of roles such as solvent, electrolyte, or precursor;colloidal suspension and reaction medium;galvanic replacement, shape-controlling, decoration, or extractive agent;finally oxidant. These roles are relevant to several methods of green hydrogen generation, including electrocatalysis, photocatalysis, and fermentation. As such, it is of utmost importance to screen potential DES formulations and determine how they can function in and contribute throughout the green hydrogen mobility stages. The realization of super green hydrogen generation stands out as a pivotal milestone in our journey towards achieving a more sustainable form of development;DESs have great potential in making this milestone achievable. Overall, incorporating DESs in hydrogen generation constitutes a promising research area and offers potential scalability for green hydrogen production, storage,transport, and utilization.

关 键 词：Watersplitting BIOHYDROGEN Super green hydrogen ELECTROCATALYSIS PHOTOCATALYSIS Fuel cell Power-to-X 

分 类 号：TQ116.2[化学工程—无机化工] TQ413