三维蜂窝碳的研究进展综述:性能和应用  

Review on the research progress of three-dimensional honeycomb carbon:Properties and applications

作　　者：谢璐 蔡信强 赵帅 倪勇[3] 蓝玉成 朱汉兴 陈元平 杨金波[7] 高飞 魏宇杰[2,9] 王文瑞 彭庆[2,9,10] XIE Lu;CAI XinQiang;ZHAO Shuai;NI Yong;LAN YuCheng;ZHU HanXing;CHEN YuanPing;YANG JinBo;GAO Fei;WEI Yujie;WANG WenRui;PENG Qing(School of Mechanical Engineering,University of Science and Technology Bejing,Beijing 100083,China;State Key Laboratory of Nonlinearity,Institute of Mechanics,Chinese Academy of Sciences,Beijing 100190,China;Department of Modern Mechanics,China University of Science and Technology,Hefei 230026,China;Department of Physics and Enginring Physics,Morgan State Universiy,Baltimore MD21251;School of Engineering,Cardif University,Cardiff CF243A,UK;School of Physics and Electronic Engineering,Jiangsu University,Zhenjiang 212013,China;School of Physics,Peking University Bejing 100871,China;Nuclear Engineering and Radiological SciencesUniversityof Michigan,AnnArbor MI48109,UA;School of Engineering Science,University of Chinese Academy of Sciences,Beijing 100049,China;Guangdong Aerospace Research Academy,Guangzhou 511458,China)

机构地区：[1]北京科技大学机械工程学院,北京100083 [2]中国科学院力学研究所,非线性国家重点研究室,北京100190 [3]中国科学技术大学近代力学系,合肥230026 [4]Department of Physics and Engineering Physics,Morgan State University,Baltimore MD 21251,USA [5]School of Engineering,Cardiff University,Cardiff CF243AA,UK [6]江苏大学物理与电子工程学院,镇江212013 [7]北京大学物理学院,北京100871 [8]Nuclear Engineering and Radiological Sciences,University of Michigan,Ann Arbor MI 48109,USA [9]中国科学院大学工程科学学院,北京100049 [10]广东空天科技研究院,广州511458

出　　处：《中国科学：物理学、力学、天文学》2024年第5期97-128,共32页Scientia Sinica Physica,Mechanica & Astronomica

基　　金：国家自然科学基金(编号:12272378);力英计划(编号:E1Z1011001);广东省高水平创新研究院项目(编号:2020B0909010003);国家重点基础研究发展计划(编号:2022YFA1203602)资助。

摘　　要：蜂窝碳结构是由石墨烯纳米片构成的蜂窝状三维纳米多孔结构,具有低密度和高比表面积和孔隙率,同时也呈现出了如机械性能、热学性质等诸多优异性能,也为该材料在纳米电子器件、光电器件、热管理、催化、机械材料强化等领域提供了广阔的应用前景.本文讨论了蜂窝碳的一些可能的晶体结构,总结了文献报道的热性能和机械性能,阐述了蜂窝碳在气体存储、水净化和热力学等方面的应用.最后对相应的三维石墨烯结构进行了一定程度的延伸,并对该结构以及蜂窝碳在制备、性能、应用等方面做出了适当的总结和展望.Honeycomb carbon has a honeycomb three-dimensional nanoporous structure comprising of graphene nanosheets and has low density,high specific surface area,and high porosity.In addition,it demonstrates numerous unique properties,such as anisotropic thermal conductivity and mechanical properties,gas and liquid ability,and applicability as a composite matrix,and a water desalination membrane.Thus,its unique structure gives honeycomb carbon great application potential in many scientific and engineering fields.Meanwhile,its mechanical and thermal properties play an indispensable role in practical engineering applications.In this review,we discuss the possible crystal structures of the honeycomb carbon.Furthermore,its thermal and mechanical properties reported in the literature are summarized in this review,and the applications of the honeycomb carbon for gas storage and water purification are explored.Finally,the corresponding three-dimensional graphene structure is extended to some degree,and the preparation,properties,and applications of this structure and honeycomb carbon are summarized and prospected.

关 键 词：蜂窝结构 石墨烯 力学性能 导热系数 气体吸附 海水淡化 

分 类 号：TQ127.11[化学工程—无机化工]