电化学介导的氧化羧化及二氧化碳还原羧化制备羧酸的研究进展  

Research Progress in Preparation of Carboxylic Acids by Electrochemical Mediated Oxidative Carboxylation and Reductive Carboxylation of Carbon Dioxide

作　　者：吕帅 朱钢国[1] 姚金忠[2] 周宏伟[2] Lv Shuai;Zhu Gangguo;Yao Jinzhong;Zhou Hongwei(College of Chemistry and Materials Science,Zhejiang Normal University,Jinhua,Zhejiang 321004;College of Biological,Chemical Sciences and Engineering,Jiaxing University,Jiaxing,Zhejiang 314001)

机构地区：[1]浙江师范大学化学与材料科学学院,浙江金华321004 [2]嘉兴学院生物与化学工程学院,浙江嘉兴314001

出　　处：《有机化学》2024年第3期780-808,共29页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(No.22071082)资助项目。

摘　　要：作为常见的一类重要化合物,羧酸被广泛应用于医药、农药和聚合物等领域,因此,探究高效且温和的羧酸合成方法具有重要意义.电化学合成羧酸因其环境友好、条件温和等优点,引起人们广泛关注.根据反应机理不同,主要从电化学氧化羧化、电化学二氧化碳还原羧化两方面出发,对电化学合成羧酸这一领域近年来的相关研究做了综述.As a class of common and important compounds,carboxylic acids are widely used in areas of medicine,pesticides and polymers.Therefore,development of facile and efficient methods for the synthesis of carboxylic acids is of great significance.Electrochemical synthesis of carboxylic acids has attracted widespread attentions due to its environmentally friendly and mild conditions.This article mainly reviews the relevant research in electrochemical synthesis of carboxylic acids in recent years from two aspects:electrochemical oxidation for carboxylation and electrochemical reduction of carbon dioxide for carboxylation.

关 键 词：电化学 羧酸 氧化羧化 还原羧化 二氧化碳 

分 类 号：O622.5[理学—有机化学]