光氯化合成氯代碳酸乙烯酯反应工艺与动力学研究  

Reaction process and kinetics of photochlorination synthesis of chloroethylene carbonate

作　　者：严楚楚 程双 袁茂全 田翔 隋志军[1] YAN Chu-chu;CHENG Shuang;YUAN Mao-quan;TIAN Xiang;SUI Zhi-jun(Chemical Engineering Institute,East China University of Science and Technology,Shanghai 200237,China;Wujing Branch of Shanghai Research Institute of Chemical Industry,Shanghai 200241,China;Shanghai Research Center for Computational Chemistry and Chemical Engineering,Shanghai 200241,China)

机构地区：[1]华东理工大学化工学院,上海200237 [2]上海化工研究院吴泾分院,上海200241 [3]上海计算化学与化工工程技术研究中心,上海200241

出　　处：《应用化工》2024年第5期1027-1030,1035,共5页Applied Chemical Industry

基　　金：国家自然科学基金(22278130)。

摘　　要：以碳酸乙烯酯和氯气为原料,在紫外灯引发条件下,合成氯代碳酸乙烯酯。考察光源功率、氯气流量和温度对光氯化反应的影响,并探究光氯化串联反应动力学。结果表明,实验最佳工艺条件为:单位体积输入功率为13.6 W/L的紫外灯,反应温度优选60℃,氯气流量范围500~750 mL/min。光氯化主副反应的表观活化能分别为7.98 kJ/mol和11.37 kJ/mol。该动力学模型为后续多级串联反应器工业化设计提供了重要支撑。Using vinyl carbonate and chlorine gas as raw materials,chloroethylene carbonate is synthesized under the condition of UV lamp initiation.The effects of light source power,chlorine concentration and temperature on photochlorination reaction were investigated,and the photochlorination tandem reaction kinetics were explored.The results show that the optimal process conditions for the experiment are:the input power per unit volume is 13.6 W/L UV lamp,the reaction temperature is preferably 60℃,and the chlorine flow range is 500~750 mL/min。The kinetics experimental results showed that the apparent activation energy for photochlorination main and side reaction were 7.98 kJ/mol and 11.37 kJ/mol respectively.The residual error distributions and the statistic tests showed that the proposed kinetic models were reliable and adequate.

关 键 词：碳酸乙烯酯 氯代碳酸乙烯酯 光氯化反应 合成工艺 动力学 

分 类 号：TQ643.1[化学工程—精细化工]