低渗透致密油藏压裂驱油剂润湿性评价及效果  

Wettability Evaluation and Effect of Fracturing Oil Displacement Agent in Low-permeability Tight Reservoirs

作　　者：陈贝尔 杨立安 李建山[3] 罗向荣[1,2] 潘谦宏 任晓娟[1,2] CHEN Beier;YANG Li’an;LI Jianshan;LUO Xiangrong;PAN Qianhong;REN Xiaojuan(Engineering Research Center of Development and Management for Low to Extra-Low Permeability Oil&Gas Reservoirs in West China,Ministry of Education,Xi’an Shiyou University,Xi’an,Shaanxi 710065,P R of China;School of Petroleum Engineering,Xi’an Shiyou University,Xi’an,Shaanxi 710065,P R of China;Oil&Gas Technology Research Institute,PetroChina Changqing Oilfield Company,Xi’an,Shaanxi 710018,P R of China;Xi’an Changqing Chemical Group Company,Ltd,Xi’an,Shaanxi 710018,P R of China)

机构地区：[1]西安石油大学西部低渗—特低渗油藏开发与治理教育部工程研究中心,陕西西安710065 [2]西安石油大学石油工程学院,陕西西安710065 [3]中国石油长庆油田分公司油气工艺研究院,陕西西安710018 [4]西安长庆化工集团有限公司,陕西西安710018

出　　处：《油田化学》2024年第2期343-349,380,共8页Oilfield Chemistry

基　　金：国家自然科学基金项目“VES磨料浆体非牛顿流动及射流冲蚀机理研究”(项目编号52074220);陕西省自然科学基础研究计划项目“页岩气藏CO_(2)混合压裂缝面溶蚀机制及裂缝导流能力的响应特征”(项目编号2021JQ-599)。

摘　　要：针对低渗透致密油藏压裂驱油剂的润湿性评价问题,分析现有接触角法的误差及不确定性,提出了评价压裂驱油剂润湿性的改进方法,采用润湿倾向指数,即驱油剂与蒸馏水在亲水/油表面的润湿接触角的比值来表征压裂驱油剂的润湿性改变方向和程度。结果表明,用接触角和接触角变化的最大值反映驱油剂对储层润湿性改变方向和能力都存在一定的不确定性。亲水表面的性质非常稳定,润湿接触角偏差较小,但亲油表面的润湿接触角偏差较大。蒸馏水与亲水/油表面润湿接触角的相对平均偏差分别为0.281%、8.929%。另外,部分驱油剂在亲水/油表面的接触角最大变化值差异不明显。用润湿倾向指数可较好地表征驱油剂的润湿性改变程度。润湿倾向指数不确定度远小于接触角不确定度。0.2%磺酸盐类驱油剂、聚氧乙烯醚类驱油剂、氟碳类驱油剂在亲水表面的接触角(润湿30 s)不确定度分别为1.24、3.11、0.64,而水润湿倾向指数不确定度分别为2.48×10^(-2)、6.33×10^(-2)、1.76×10^(-2)。通过Amott方法,测得7种压裂驱油剂作用下天然岩样的水湿指数。该水湿指数从大到小的排序与用接触角法测得的水润湿倾向指数从小到大的顺序一致。两种方法的测试结果进一步证实了使用润湿倾向指数的准确性和优越性。该方法有利于快捷地评价压裂驱油剂对储层润湿性的改变能力,优选低渗透致密油藏压裂驱油剂。Aiming at the wettability evaluation of fracturing oil displacement agents in low-permeability tight reservoirs,the error and uncertainty of the existing contact angle method were analyzed.An improved method for evaluating the wettability of fracturing oil displacement agents was proposed.The wettability tendency index,i.e.,the ratio of wetting contact angle between oil displacement agents and distilled water on the hydrophilic/lipophilic surfaces,was used to characterize the wettability change direction and degree of fracturing oil displacement agents.The results showed that there was some uncertainty in reflecting both the direction and ability of the oil displacement agent to change the reservoir wettability by the contact angle and the maximum value of the contact angle change.Hydrophilic surfaces were very stable and had small deviations in wetting contact angle,while lipophilic surfaces had large deviations in wetting contact angle.The relative average deviations of the wetting contact angles between distilled water and hydrophilic/lipophilic surfaces were 0.281% and 8.929%,respectively.In addition,the differences in the maximum change values of contact angles of some oil displacement agents on hydrophilic/lipophilic surfaces were not obvious.The wettability change degree of oil displacement agents could be better characterized by wetting tendency index.The uncertainty of wetting tendency index was much smaller than that of contact angle.The uncertainties of contact angle(wetting for 30 s)of 0.2% sulfonate oil displacement agents,polyoxyethylene ether oil displacement agents and fluorocarbon oil displacement agents on hydrophilic surfaces were 1.24,3.11 and 0.64,respectively,while their uncertainties of water wetting tendency index were 2.48×10^(-2),6.33×10^(-2) and 1.76×10^(-2),respectively.The water-wetting index of natural rock samples under the effect of seven fracturing oil displacement agents was measured by the Amott method.The order of this water-wetting index from largest to smallest was consist

关 键 词：低渗透 致密油藏 压裂驱油剂 润湿性 接触角 润湿倾向指数 

分 类 号：TE357[石油与天然气工程—油气田开发工程]