Construction of LiCl/LiF/LiZn hybrid SEI interface achieving high-performance sulfide-based all-solid-state lithium metal batteries  

作　　者：Chaochao Wei Yujie Xiao Zhongkai Wu Chen Liu Qiyue Luo Ziling Jiang Lin Li Liang Ming Jie Yang Shijie Cheng Chuang Yu 

机构地区：[1]State Key Laboratory of Advanced Electromagnetic Technology,School of Electrical and Electronic Engineering,Huazhong University of Science and Technology,Wuhan,430074,China [2]School of Chemistry and Chemical Engineering,Huazhong University of Science and Technology,Wuhan,430074,China

出　　处：《Science China Chemistry》2024年第6期1990-2001,共12页中国科学（化学英文版）

基　　金：supported by the National Key Research and Development Program of China(2021YFB2500200);the National Natural Science Foundation of China(52177214);supported by China Fujian Energy Devices Science and Technology Innovation Laboratory Open Fund(21C-OP202211);HUST’s Analytical and Testing Center for the technical support。

摘　　要：Sulfide-based all-solid-state lithium metal batteries(ASSLMBs)have received extensive attention due to their high energy density and high safety,while the poor interface stability between sulfide electrolyte and lithium metal anode limits their development.Hence,a hybrid SEI(LICl/Li F/Li Zn)was constructed at the interface between Li_(5.5)PS_(4.5)Cl_(1.5)sulfide electrolyte and lithium metal.The Li Cl and Li F interface phases with high interface energy effectively induce the uniform deposition of Li^(+)and reduce the overpotential of Li^(+)deposition,while the Li Zn alloy interface phase accelerates the diffusion of lithium ions.The synergistic effect of the above functional interface phases inhibits the growth of lithium dendrites and stabilizes the interface between the sulfide electrolyte and lithium metal.The hybrid SEI strategy exhibits excellent electrochemical performance on symmetric batteries and all-solid-state batteries.The symmetrical cell exhibits stable cycling performance over long duration over 500 h at 1.0 mA cm^(-2).Moreover,the LiNbO_(3)@NCM712/Li_(5.5)PS_(4.5)Cl_(1.5)/Li-10%Zn F_(2)battery exhibits excellent cycle stability at a high rate of 0.5 C,with a capacity retention rate of 76.4%after 350 cycles.

关 键 词：argyrodite electrolytes ASSLMBs electrochemical stability Li-ZnF_2 anode electrochemical performance 

分 类 号：TM912[电气工程—电力电子与电力传动] O646[理学—物理化学]