Corrosion evaluation and resistance study of alloys in chloride salts for concentrating solar power plants  

作　　者：Dong-Mei Han Yong Shuai Bachirou Guene Lougou Bo-Xi Geng Xi-Bo He Tian-Tian Yan Jia-Meng Song 

机构地区：[1]School of Energy Science and Engineering,Harbin Institute of Technology,Harbin,150001,China

出　　处：《Rare Metals》2024年第3期1222-1233,共12页稀有金属（英文版）

基　　金：financially supported by the China National Key Research and Development Plan Project(No.2018YFA0702300);the National Natural Science Foundation of China(Nos.52227813 and 51950410590)。

摘　　要：Thermal energy storage(TES)systems based on molten salt are widely used in concentrating solar power(CSP)plants.The investigation of the corrosion behavior of alloy materials in molten salt is crucial for the correct selection of alloy materials and the design of TES systems.In this study,the corrosion behavior of 304,310S,316,and In625 alloys in molten chloride salts(27 mol%NaCl-22 mol%KCl-51 mol%MgCl,)was investigated.The evolution of mass loss of the alloy samples with corrosion time and temperature and the analysis of the experimental results by scanning electron microscopy(SEM),energy dispersive spectrometer(EDS),and X-ray diffraction(XRD)revealed the corrosion mechanism of the alloy samples in molten chloride salts.The main factors affecting the corrosion of the alloy samples were further analyzed.It was found that the loose multi-layer corrosion was formed on the surface of the corroded alloy samples with the increase in corrosion degree.Moreover,the experimental results.showed that Mo played a positive role in improving the corrosion resistance of the alloy samples because the presence of Mo could inhibit the outward diffusion of alloying element Cr.This work enriches the molten salt corrosion database and provides a reference for the selection of alloy materials for TES systems with potential application in CSP plants.

关 键 词：Thermal energy storage Molten chloride salt Alloy materials Corrosion mechanism Corrosion resistance 

分 类 号：TM615[电气工程—电力系统及自动化] TG172[金属学及工艺—金属表面处理]