光电化学水分解中基于半导体的界面工程策略和载流子动力学表征技术的研究进展  

Advancements in semiconductor-based interface engineering strategies and characterization techniques for carrier dynamics in photoelectrochemical water splitting

作　　者：张生雅 杜佩瑶 卢小泉 Shengya Zhang;Peiyao Du;Xiaoquan Lu(Key Laboratory of Water Environment Protection in Plateau Intersection(Ministry of Education),Key Laboratory of Bioelectrochemistry&Environmental Analysis of Gansu Province,College of Chemistry&Chemical Engineering,Northwest Normal University,Lanzhou,730070,China;College of Chemistry&Pharmacy,Northwest A&F University,Yangling,712100,China)

机构地区：[1]Key Laboratory of Water Environment Protection in Plateau Intersection(Ministry of Education),Key Laboratory of Bioelectrochemistry&Environmental Analysis of Gansu Province,College of Chemistry&Chemical Engineering,Northwest Normal University,Lanzhou,730070,China [2]College of Chemistry&Pharmacy,Northwest A&F University,Yangling,712100,China

出　　处：《Science China Materials》2024年第5期1379-1392,共14页中国科学（材料科学）（英文版）

基　　金：the National Natural Science Foundation of China(22127803,22222408,22174110 and 22001193);the Industrial Support Plan of Gansu Provincial Department of Education(2021cyzc-01);the Special Fund Project for Guiding Local Scientific and Technological Development by the Central Government(2020-2060503-17);the Qin Chuangyuan Innovation and Entrepreneurship Talent Project(QCYRCXM-2022-338)。

摘　　要：为了缓解能源危机和环境问题,太阳能的应用受到了人们的广泛关注.光电化学水分解是一种极有前景的、可以将清洁可再生太阳能转化为清洁燃料的技术.提高能量转换效率无疑是光电化学水分解技术的关键.光生载流子的分离和转移速率是影响光电化学性能的主要因素之一.本综述简要介绍了一些界面工程策略以增强光阳极中光生载流子的分离和传输.此外,总结了近期在原位量化光生载流子传输动力学研究中的进展.我们的目的是帮助读者了解这一领域的最新发展,并为理解动态空穴转移提供一个独特的视角.最后,我们对发展微纳尺度电极界面光生载流子分离和转移动力学表征手段中面临的重大挑战和未来前景进行了展望.The application of solar energy has garnered significant attention for alleviating the energy crisis and addressing environmental issues.Photoelectrochemical(PEC)water splitting is a promising technology for converting renewable solar energy into chemical fuels.Improving the efficiency of energy conversion is undoubtedly crucial for PEC water splitting technology.One of the primary factors that affect PEC performance is the rate of separation and transfer of photogenerated carriers.In this review,some interface engineering strategies for enhancing the separation and transfer of photogenerated charge carriers in a photoanode are briefly presented.Furthermore,recent state-of-the-art advancements in quantifying photogenerated carrier dynamics are summarized.Our purpose is to help readers understand the latest developments in this field and provide a unique perspective for understanding dynamic hole transfer.Finally,a critical perspective is presented on the significant challenges and prospects for developing characterization methods aimed at studying the separation and transfer kinetics of photogenerated carrier at micro-nanoelectrode interfaces.

关 键 词：photoelectrochemical water splitting photogenerated carrier dynamics interface engineering strategy scanning photoelectrochemical microscopy(SPECM) 

分 类 号：TQ151.1[化学工程—电化学工业]