TiO_(2)粒径对TiO_(2)/聚脲超疏水涂层机械稳定性和防覆冰性能的影响研究  

Effect of TiO_(2)Particle Size on the Mechanical Stability and Anti-icing Performance of TiO_(2)/Polyurea Superhydrophobic Coatings

作　　者：胡丽娜 杜一枝 董立婷 雷煜航 HU Lina;DU Yizhi;DONG Liting;LEI Yuhang(School of Electrical Engineering,Xinjiang University,Urumqi 830047,China)

机构地区：[1]新疆大学电气工程学院,乌鲁木齐830047

出　　处：《表面技术》2024年第12期240-251,共12页Surface Technology

基　　金：自治区重点研发任务专项(2022B03028-4);省部级高层次人才引进计划(TCBR202106);省部级自然科学青年基金(2021D01C100)。

摘　　要：目的研究改性TiO_(2)粒径对TiO_(2)/聚脲超疏水涂层机械稳定性和防覆冰性能的影响,解决低温环境下风机叶片结冰问题。方法采用有机无机粒子共混,以改性纳米TiO_(2)和聚天门冬氨酸酯聚脲(PAE聚脲)为材料,利用一步法构建TiO_(2)/PAE聚脲超疏水涂层。开展耐酸碱性、耐磨性、静态防覆冰、动态防覆冰、覆冰黏结强度等实验研究,并应用在真实风电场。结果超疏水涂层的机械稳定性、防覆冰性能随着粒径增大而逐渐变差。当TiO_(2)粉末粒径为100 nm时,接触角为(162.4±2.1)°,滚动角为(3.8±0.7)°;经过250次磨损,接触角为(158.8±0.31)°,滚动角为(7.3±0.1)°;经过14 d的酸碱耐候性实验,超疏水涂层仍具有超疏水性,酸性和碱性溶液皆会导致涂层受损,碱性溶液对涂层腐蚀作用更强;机械稳定性较强、防覆冰性能较优。涂有超疏水涂层的风机在冻雨天平均比空白风机平均多运行255 min,对一台2 MW机组来讲,相当于多产生8500 kW·h的电能。结论制备的超疏水涂层具备优良的机械稳定性与防覆冰性能,推动了超疏水涂层在风机叶片被动防覆冰领域的应用。The status of wind power in China's energy structure has risen to the third place,but 54%of unit downtime is caused by icing.For this reason,it is very important to carry out anti-icing work on wind turbine blades to ensure the safe operation of wind turbines.In prior research,scientists frequently utilized PTFE,PVDF,and polypyrrole polymers to produce hydrophobic coatings in order to address the icing issue of wind turbine blades.The drawbacks of these coatings included their high cost,lack of durability and biodegradability.To overcome the shortcomings of current methods,the work aims to introduce a robust superhydrophobic coating with exceptional durability,a straightforward preparation process,and significant anti-icing capabilities.It is designed to fulfill the outdoor operational demands of wind turbine blades.Additionally,the impact of four different TiO_(2)particle sizes on various properties of the coating was explored,including its linear abrasion resistance,acid and alkali resistance,anti-icing characteristics,and icing bond strength.Then,the comprehensive analysis was carried out to provide technical insights for preventing ice accumulation on wind turbines in icing-prone regions.Micro-nano composite superhydrophobic coating was developed with TiO_(2)nanoparticles and poly(aspartate)polyurea(PAE polyurea),and its mechanical stability and anti-icing performance were tested.The effect of the coating on ice coverage delay was examined during the freezing procedure.TiO_(2)particles of 100 nm exhibited a contact angle of 162.4°and a rolling angle of 3.8°,and the anti-icing performance and mechanical stability of the samples were better.The superhydrophobic coatings prepared by 100,200,and 500 nm TiO_(2)still maintained good superhydrophobicity after 250 linear friction tests and the superhydrophobic coatings prepared by 1μm TiO_(2)maintained a certain degree of hydrophobicity.The superhydrophobic coatings retained their excellent superhydrophobicity even after being immersed in acidic,neutral,and alkali

关 键 词：超疏水涂层 防覆冰性能 机械稳定性 改性TiO_(2)粒子 粒子粒径 风机叶片 

分 类 号：TB34[一般工业技术—材料科学与工程]