Recent Advances in Enantioselective Reactions of Terminal Unactivated Alkenes  

作　　者：Qihang Guo Xuzhong Shen Zhan Lu 

机构地区：[1]Centerof ChemistryforFrontier Technologies,Departmentof Chemistry,Zhejiang University,Hangzhou,Zhejiang 310058,China [2]ZJU-Hangzhou Global Scientific and Technological Innovation Center,Hangzhou,Zhejiang 311215,China [3]College of Chemistry,Zhengzhou University,Zhengzhou,Henan 450001,China

出　　处：《Chinese Journal of Chemistry》2024年第7期760-776,共17页中国化学（英文版）

基　　金：supports were provided by National Key R&D Program of China (2021YFA1500200 and 2021YFF0701600);NSFC (22271249);the Fundamental Research Funds for the Central Universities (226-2022-00224 and 226-2023-00115).

摘　　要：α-Olefins as aliphatic terminal alkenes could be obtained easily from numerous contemporary synthetic reactions as well as petro-chemical industry,and also found in natural products.Compared to the alkenes attaching the directing groups or activating group,the catalytic asymmetric reaction of unactivated terminal alkenes presents great challenges due to the weak electron effect and small steric hindrance effect.This review mainly summarizes the latest progress of the asymmetric reaction of unactivated terminal olefins since 2016.

关 键 词：Asymmetric catalysis Terminal unactivated alkenes Hydrofunctionalization Difunctionalization Metal-catalyzed 

分 类 号：O62[理学—有机化学]