石墨烯/钼基二硫族化合物范德华异质结光电探测器的研究进展  

Advances in graphene/molybdenum dichalcogenide-based van der Waals heterostructure photodetectors

作　　者：张鑫华 刘伟迪 龚佑品 刘庆丰 陈志刚 ZHANG Xin-hua;LIU Wei-di;GONG You-pin;LIU Qing-feng;CHEN Zhi-gang(State Key Laboratory of Materials-Oriented Chemical Engineering,College of Chemical Engineering,Nanjing Tech University,Nanjing 211816,China;School of Chemistry and Physics,ARC Research Hub in Zero-emission Power Generation for Carbon Neutrality,and Center for Materials Science,Queensland University of Technology,Brisbane,QLD 4000,Australia;Center of Quantum Materials and Devices at Institute of Advanced Interdisciplinary Studies,College of Physics,Chongqing University,Chongqing 400044,China)

机构地区：[1]南京工业大学化工学院,材料化学工程国家重点实验室,江苏南京211816 [2]School of Chemistry and Physics,ARC Research Hub in Zero-emission Power Generation for Carbon Neutrality,and Center for Materials Science,Queensland University of Technology,Brisbane,QLD 4000,Australia [3]重庆大学物理学院,前沿交叉学科研究院量子材料与器件研究中心,重庆400044

出　　处：《新型炭材料（中英文）》2024年第3期439-457,共19页New Carbon Materials

基　　金：supported by the National Natural Science Foundation of China (51972170);the State Key Laboratory of MaterialsOriented Chemical Engineering (SKL-MCE-23A04);the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD);the Jiangsu Specially-Appointed Professor Program. CHEN Zhi-gang thanks the financial support from the Australian Research Council, and QUT Capacity Building Professor Program;support from the Chongqing Research Program of Basic Research and Frontier Technology (cstc2021jcyj-msxm X0641);the Doctoral “through train” scientific research project of Chongqing (CSTB2022BSXM-JCX0085).

摘　　要：石墨烯因其高载流子迁移率和宽光谱吸收范围而广泛应用于光电探测。然而,其低光吸收率导致的高暗电流严重限制了它的光电探测性能。钼基二硫族化合物(MoX_(2),X=S、Se和Te)具有高的吸收系数,能够弥补石墨烯基光电探测器中暗电流较高的劣势,因此基于石墨烯/MoX_(2)范德华异质结的光电探测器能够表现出优异的光电子特性。本综述首先回顾了光电探测器的工作原理、性能指标和结构。之后,从材料基础的角度突出了石墨烯/MoX_(2)范德华异质结光电探测器的重要性。接着,总结了石墨烯/MoX_(2)范德华异质结光电探测器的制备方法和性能增强策略。最后,强调了这类异质结光电探测器当前面临的挑战及未来的发展方向。本综述将为这类高性能范德华异质结光电探测器的设计提供一定的指导和参考。Graphene is widely used in photodetection because of its high carrier mobility and wide spectral absorption range.However,its high dark current caused by its low light absorption severely limits its performance.Molybdenum dihalide(MoX_(2),X=S,Se and Te)has a high absorption coefficient,which can compensate for the high dark current in graphene-based photodetectors and result in outstanding photoelectronic properties of those based on a graphene/MoX_(2) van der Waals heterostructure(vdWH).In this review,we firstly review working principles,performance indicators,and structures of photodetectors.After that,the signific-ance of graphene/MoX_(2) vdWH photodetectors is highlighted from the fundamental perspective.Preparation methodologies and per-formance enhancement strategies of graphene/MoX_(2) vdWH photodetectors are correspondingly summarized.In the end,we high-light the current challenges and future directions of the graphene/MoX_(2) vdWH photodetectors.This review will guide the design of high-performance vdWH photodetectors.

关 键 词：石墨烯 钼基二硫族化合物 异质结 光电探测器 范德华 

分 类 号：TN15[电子电信—物理电子学]