氧化亚铜改性四针状氧化锌晶须表面及其光催化性能研究  

Surface Modification of Tetrapod-Like ZnO Whisker by Cuprous Oxide and Its Photocatalytic Properties

作　　者：刘红[1] 刘花蓉[1] 范希梅[2] LIU Hong;LIU Huarong;FAN Ximei(Multicomponent Alloys Key Laboratory of Deyang City,Department of Material Engineering,Sichuan College of Architectural Technology,Deyang 618000,China;Key Laboratory of Advanced Technologies of Materials,Southwest Jiaotong University,Chengdu 610031,China)

机构地区：[1]四川建筑职业技术学院材料工程系,多组元合金德阳市重点实验室,德阳618000 [2]西南交通大学,材料先进技术教育部重点实验室,成都610031

出　　处：《人工晶体学报》2024年第6期1042-1050,共9页Journal of Synthetic Crystals

基　　金：德阳市社会发展领域重点研发指导类项目(2023SZZ143);四川建筑职业技术学院院级项目(2022KJ19);四川建筑职业技术学院科研创新团队(SCJYKYCXTD 2022)。

摘　　要：本文采用简便的液相还原法以乙二醇(EG)为还原剂,聚乙烯吡咯烷酮(PVP)为表面活性剂,制备了Cu_(2)O/T-ZnOw复合半导体催化剂样品,对样品的物相、微观形貌、禁带宽度、光致发光性能、光催化性能,以及可回收利用性能进行了详细研究。结果表明:随着PVP添加量的增加,四针状氧化锌晶须(T-ZnOw)表面沉积的Cu_(2)O由立方体形逐渐向球形转变;T-ZnOw表面沉积Cu_(2)O后可使半导体催化剂的禁带宽度(Eg)变窄,且能有效减少光生电子和空穴对的复合,使其光催化活性得到明显改善,紫外光照100 min时复合半导体催化剂对甲基橙(MO)溶液的降解率均提高到90%以上;复合催化剂中Cu_(2)O形貌不同其光催化活性有所差异,同等条件下,立方体形Cu_(2)O/T-ZnOw复合催化剂比球形Cu_(2)O/T-ZnOw表现出更好的光催化活性;同时复合催化剂样品展现出良好的可回收利用性能,经过六个周期的回收循环光催化降解试验后,样品对MO溶液的降解率仍能保持在80%以上。Cu_(2)O/T-ZnOw composite catalysts were prepared by a simple liquid-phase reduction method,in which ethylene glycol(EG)as reducing agent and polyvinyl pyrrolidone(PVP)as surfactant.The phase,morphology,band gap,photoluminescence properties,photodegradation,and recyclable performance of samples were studied in detail.The result shows that PVP plays an important role in the morphology of Cu_(2)O.It makes Cu_(2)O crystals deposited on the surface of tetrapod-like ZnO whiskers(T-ZnOw)gradually transformed from cubic to sphericity.When Cu_(2)O crystals deposited on T-ZnOw surface,the band gap(Eg)of semiconductor catalysts were narrowed,and the recombination of photogenerated electron and hole pairs were effectively reduced,which can significantly improve the photocatalytic activity of semiconductor.The degradation efficiency of methyl orange(MO)solution by composite catalysts is increased to more than 90%after 100 min UV irradiation.At the same condition,the cubic-Cu_(2)O/T-ZnOw composite shows higher photocatalytic activity than spherical-Cu_(2)O/T-ZnOw.After six recycles of photocatalytic degradation tests,the degradation rate of samples prepared by 0.06 g PVP can still be maintained more than 80%,which shows that the Cu_(2)O/T-ZnOw composites have good recyclable performance.

关 键 词：Cu_(2)O/T-ZnOw 表面沉积 PVP 甲基橙 光催化性能 降解率 可回收利用性能 

分 类 号：O643.36[理学—物理化学] O644.1[理学—化学]