Highly strengthening and toughening biomimetic ceramic structures fabricated via a novel coaxially printing  

作　　者：Kunkun Song Shengda Yang Ningqi Shao Yantang Zhao Peng He Yongfeng Wei Hengzhong Fan Yongsheng Zhang Qiangqiang Zhang 

机构地区：[1]State Key Laboratory of Solid Lubrication,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000,China [2]School of Civil Engineering and Mechanics,Lanzhou University,Lanzhou 730000,China [3]Key Laboratory of Mechanics on Disaster and Environment in Western China(Lanzhou University),Ministry of Education,Lanzhou 730000.China

出　　处：《Journal of Advanced Ceramics》2024年第4期403-412,共10页先进陶瓷（英文）

基　　金：the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB 0470303);the Fund of Natural Science Foundation of China(No.52073132);the Fundamental Research Funds for the Central Universities(Nos.zujbky-2022-ey02 and Izujbky-2023-eyt03).

摘　　要：Additive manufacturing technology,by manipulating and emulating inherent multiscale,multi-material,and multifunctional structures found in nature,has created new opportunities for constructing heterogeneous structures associated with special properties and achieving ultra-high mechanical performance and reliability in ceramic composite materials.In this study,we have developed an innovative fabrication method designated as coaxial 3D printing for the synchronous construction of two constituents into ceramic composites with a tooth enamel biomimetic microstructure.Herein,the stiff silicate and flexible epoxy served as a strengthening bridge and toughening layer,respectively.The method differed from the traditional approach of randomly dispersing reinforcing components within a ceramic matrix.It allowed for the direct creation of an internally effective three-dimensional reinforcement network structure in ceramic composites.This process facilitated synergistic deformation and simultaneous enhancement of multiple materials and hierarchical structures.Owing to the uniform distribution of internal stress and effective block of microcrack propagation,the biomimetically structured silicate/epoxy ceramic composite has demonstrated much significant enhancement in mechanical properties,includingcompressive strength(48.8±3.12MPa),flexuralstrength(10.39±1.23MPa),andflexuraltoughness(218.7±54.6kJ/m^(3)),which was 0.5,2.1,and 47.5 times as high as those of the intrinsic brittle silicate ceramics,respectively.In-situ characterization and multiscale finite element simulation of microstructural evolution during three-point bending deformation further validated multiple-step features of the fracture process(silicate bridge fracture,interface detachment,epoxy extraction,and rupture),which benefited from interpenetrating structural features achieved by coaxial printing to accomplish with the complex propagating routines of the crack deflection in silicate ceramic composites.This coaxial 3D printing method paves the way for tailor

关 键 词：coaxial 3D printing silicate ceramic composites enamel biomimetic microstructure strengthening bridge tougheninglayer crackdeflection 

分 类 号：TM911.4[电气工程—电力电子与电力传动] TB383.2[一般工业技术—材料科学与工程]