一种蒽醌基氟硼化合物光学和黏度性能研究  

Research on the Optical and Viscosity Properties of an NovelAnthraquinone-based Difluoroboron Compound

作　　者：周昊 梁芮 杨舒帆 高树林 杨艳华 ZHOU Hao;LIANG Rui;YANG Shufan;GAO Shulin;YANG Yanhua(School of Chemistry and Chemical Engineering,Kunming University,Kunming,Yunnan,China 650214)

机构地区：[1]昆明学院化学化工学院,云南昆明650214

出　　处：《昆明学院学报》2024年第3期76-81,共6页Journal of Kunming University

基　　金：云南省“兴滇英才支持计划”青年人才专项项目(ZX20230278);昆明学院引进人才科研项目(YJL2008)。

摘　　要：蒽醌基团由于独特的生化活性,已被广泛应用于药物研发和生物探针领域.为进一步探究蒽醌化合物的光学性能,以2-氨基蒽醌为原料,经亲核取代反应、还原反应、亲核加成反应和配位反应,制备出一种含有蒽醌基团的氟硼化合物,并对其进行光学性能测试.结果表明,该化合物在不同极性有机溶剂中显示分子内电荷转移特性,在四氢呋喃/水和甲醇/甘油混合溶剂中,分别具有聚集诱导发光性能和黏度特性.Anthraquinone group has been widely used in fields of drug development and bioprobe due to their unique biochemical activity.To further investigate the optical properties of anthraquinone compounds,a novel anthraquinone-based difluoroboron compound was prepared using 2-aminoanthraquinone as raw material,through nucleophilic substitution,reduction,nucleophilic addition and coordination reaction,and its optical property was measured.The results showed that the synthesized compound exhibited intramolecular charge transfer characteristic in different polar organic solvents,and displayed aggregation-induced emission property and viscosity property in tetrahydrofuran/water and methanol/glycerol mixed solvent,respectively.

关 键 词：蒽醌基团 氟硼化合物 聚集诱导发光 黏度特性 

分 类 号：O626.32[理学—有机化学] O622.6[理学—化学]