Tungsten separation behavior on preparation of high-purity cerium by combined vacuum gravity sedimentation-directional solidification  

作　　者：Dongwei Zhang Wenli Lu Minglei Xu Dehong Chen Xiaowei Zhang Chuang Yu Wensheng Yang Ruifeng Dong Zhiqiang Wang Liguo Han Zengdong Pang 

机构地区：[1]GRIREM Hi-Tech Co.,Ltd.,Langfang,065201,China [2]National Engineering Research Center for Rare Earth,China GRINM Group Co.,Ltd.,Beijing,100088,China [3]GRIREM Advanced Materials Co.,Ltd.,Beijing,100088,China

出　　处：《Journal of Rare Earths》2024年第6期1182-1186,I0007,共6页稀土学报（英文版）

基　　金：Project supported by the National Key Research and Development Program of China(2022YFC2905203);the NationalScience and Technology Major Project of China(J2019-VI-0023-0140)。

摘　　要：In light of the difficult removal of harmful impurity tungsten(W)in Ce metal,in this paper a combined vacuum gravity sedimentation-directional solidification method was innovatively designed and the W separation behavior was investigated.By reducing the electron beam power instantly and gradually at reduction rates of 1,3 and 5 kW/min,it is found that W is enriched at the bottom of ingots as the melt solidifies.The enrichment effect is much better than that of single purification method and the enrichment degree increases as the beam reduction rate decreases,attributed to the k0(W)>1 andρ(W)>ρ(Ce).Overall,the minimum content of W impurity can decrease from 630 to 0.1 ppm at the top of the ingot,and the purity of Ce increases from 99.932 wt%to 99.995 wt%by this combined method.Additionally,this paper provides a new method for the removal of high density and low evaporation coefficient impurities in low vapor pressure rare earth metals.

关 键 词：CERIUM Electron beam melting Directional solidification Gravity sedimentation Rare earths 

分 类 号：TF845[冶金工程—有色金属冶金]