二维材料纳米油墨的制备及喷墨打印研究进展  

Progress in the preparation and ink-jet printing of 2D material-based nano-inks

作　　者：张妤欣 黄孝东 陈迪[1] 邓杭军 王文俊[1] 刘平伟[1] ZHANG Yuxin;HUANG Xiaodong;CHEN Di;DENG Hangjun;WANG Wenjun;LIU Pingwei(State Key Laboratory of Chemical Engineering,Zhejiang University,Hangzhou 310058,Zhejiang,China;Zhejiang NHU Special Materials Company Limited,Shaoxing 312369,Zhejiang,China)

机构地区：[1]浙江大学化学工程联合国家重点实验室,浙江杭州310058 [2]浙江新和成特种材料有限公司,浙江绍兴312369

出　　处：《化工进展》2024年第6期3145-3158,共14页Chemical Industry and Engineering Progress

基　　金：国家自然科学基金(22293061,22078289);浙江省“尖兵”、“领雁”研发攻关计划(2023C01094)。

摘　　要：以石墨烯为代表的二维材料具有出色的综合性能,可用其制作功能纳米油墨,通过喷墨打印可加工得到光电功能器件,其在能源、环境、生命健康等领域具有广阔的应用前景。本文总结了几种典型二维材料的性能、其纳米油墨的制备及喷墨打印应用等,重点介绍了液相剥离和喷墨打印过程的调控。对比不同剥离方法及原理,并对喷墨打印相关理论如咖啡环效应、马兰戈尼效应等进行综述。指出可通过对二维材料剥离过程及其纳米油墨打印过程的精准调控,形成基于喷墨打印的先进微纳制造技术,实现不同功能微纳电子元件和器件的低成本加工,推动生物传感、柔性电子等领域的发展。Two-dimensional materials represented by graphene possess excellent comprehensive performance,which can be used to manufacture functional nano-inks and obtain optoelectronic functional devices by ink-jet printing.There are broad application prospects in the fields of energy,environment,life and health.This paper systematically summarized the properties of several typical two-dimensional materials,the preparation of nano-inks and the application of ink-jet printing,focusing on the regulation of liquid phase exfoliation and ink-jet printing processes.Different exfoliation methods and principles were summarized and compared,as well as the related theories of ink-jet printing,such as the coffee ring effect and Marangoni effect,were reviewed.Through the precise regulation of the two-dimensional material exfoliation process and its nano-inks printing process,it was expected to form an advanced micro-nano manufacturing technology based on ink-jet printing,realize the low-cost processing of different functional micro-nano electronic components and devices,and promote the development of biosensing,flexible electronics and other fields.

关 键 词：二维材料 液相剥离 纳米油墨 喷墨打印 电子器件 

分 类 号：TQ11[化学工程—无机化工]