Access to Versatile Functionalized Cu(Ⅲ) Complexes Enabled by Direct Transmetalation to Well-Defined Copper(Ⅲ) Fluoride Complex Me_(4)N^(+)[Cu(CF_(3))_(3)F]^(-)  

作　　者：Guangyu Wang Huaiyuan Li Xuebing Leng Long Lu Qilong Shen 

机构地区：[1]Key Laboratory of Fluorine and Nitrogen Chemistry and Advanced Materials,Shanghai Institute of Organic Chemistry,University of Chinese Academy of Sciences,Chinese Academy of Sciences,345 Lingling Lu,Shanghai 200032,China

出　　处：《Chinese Journal of Chemistry》2024年第10期1107-1113,共7页中国化学（英文版）

基　　金：the financial support from the National Key Research and Development Program of China(No.2021YFF0701700);the National Natural Science Foundation of China(22061160465).

摘　　要：The invention of a well-defined Cu(Ⅲ)fluoride complex Me_(4)N^(+)[Cu(CF_(3))_(3)(F)]^(-)1 enabled to access a versatile of functionalized Cu(Ⅲ)complexes[Me_(4)N]^(+)[Cu(X)(CF_(3))_(3)]^(-)(X=C_(6)F_(5),C_(6)F_(5)C≡C,CN,Cl,N_(3),^(t)BuOO,SCN,OAc,SAr),many of them for the first time.The availability of these complexes allowed us to evaluate the trans-influence order of ligand in Cu(Ⅲ)complexes:Bn>CF_(3)^(-)>C_(6)F_(5)^(-)>N_(3)^(-)>py~CH_(3)^(-)~C_(6)F_(5)C≡C>NO_(2)PhO^(-)~^(t)BuOO^(-)~CH_(3)COO^(-)>F^(-).

关 键 词：FLUORINE COPPER Cu(Ⅲ) Cu(Ⅲ)fluoride TRIFLUOROMETHYL 

分 类 号：O64[理学—物理化学]