CO_(2)的N-甲酰化反应研究进展  

PROGRESS IN N-FORMYLATION OF CARBON DIOXIDE

作　　者：郭旭 何鑫 徐润 夏国富 Guo Xu;He Xin;Xu Run;Xia Guofu(SINOPEC Research Institute of Petroleum Processing Co.,Ltd.,Beijing 100083)

机构地区：[1]中石化石油化工科学研究院有限公司,北京100083

出　　处：《石油炼制与化工》2024年第7期152-162,共11页Petroleum Processing and Petrochemicals

摘　　要：二氧化碳(CO_(2))的N-甲酰化反应是CO_(2)在还原剂的作用下,与有机胺类化合物反应生成N-甲酰胺类化合物的反应。CO_(2)的N-甲酰化反应既能够实现CO_(2)的资源化利用,有助于减少温室气体排放,同时能够将廉价的CO_(2)转化为高附加值的有机化学品,如N,N-二甲基甲酰胺和N-甲酰吗啉等,拓展CO_(2)下游转化利用的反应网络。对近年来CO_(2)的N-甲酰化反应的催化剂体系、催化机理和反应工艺等方面进行综述,阐述该反应研究过程中所面临的问题,并展望其未来发展方向。N-formylation of carbon dioxide(CO_(2))is the reaction of CO_(2)with organic amine in the presence of a reducing agent to form N-formamide compound.The N-formylation reaction of CO_(2)can be used as a resources to reduce greenhouse gas emissions,andcan convert cheap CO_(2)into highvalue-added organic chemicals such as N,N-dimethylformamide and N-formylmorpholine,etc.,expandsthe CO_(2)downstream conversion and utilization of the reaction network.Inthis paper,the catalyst system,catalytic mechanism,and reaction process of N-formylation of CO_(2)in recent yearswere reviewed,and the problems in the research and future developmentof the reactionwere also discussed.

关 键 词：CO_(2) N-甲酰化 催化剂 反应工艺 

分 类 号：O621.256.1[理学—有机化学]