有机硅高沸物催化裂解技术进展  

Research Process of Catalytic Pyrolysis Technology of Organosilicon High Boiling Residues

作　　者：刘周恩[1,2] 颜昌锐 陈锦溢 王文金 华超 甘周清[3] LIU Zhouen;YAN Changyue;CHEN Jinyi;WANG Wenjin;HUA Chao;GAN Zhouqing(Institute of Processing Engineering,Chinese Academy of Sciences,Beijing 100191,China;Hubei Tree Gorges Laboratory,Yichang Hubei 443007,China;Hubei Xingrui Silicon Materials Group Co.,Ltd.,Yichang Hubei 443007,China)

机构地区：[1]中国科学院过程工程研究所,北京100191 [2]湖北三峡实验室,湖北宜昌443007 [3]湖北兴瑞硅材料有限公司,湖北宜昌443007

出　　处：《辽宁化工》2024年第6期829-832,836,共5页Liaoning Chemical Industry

基　　金：湖北三峡实验室创新基金项目(项目编号:SC214002);宁夏回族自治区重点研发计划项目(项目编号:2022BFH020007)。

摘　　要：催化裂解技术可高效低能耗地资源化处理利用有机硅高沸物,有机硅高沸物催化裂解技术根据所用催化剂不同可分为氯化铝基催化裂解技术、有机胺基催化裂解技术、钯磷配位化合物基催化裂解技术、磷酸盐基催化裂解技术、过渡金属及其化合物基催化裂解技术、分子筛和活性炭基催化裂解技术等。对这些技术的特点、发展现状和趋势进行了研究,为有效利用这些技术对有机硅高沸物通过催化裂解实现资源化处理利用提供技术支持。研究表明,有机胺基催化裂解技术相对其他技术具有其他技术无可比拟的技术优势,是未来有机硅高沸物催化裂解技术发展的一个趋势和热点。By the catalytic pyrolysis technology,the resource utilization treatment of organosilicon high boiling residues can be realized with high efficiency and low energy consumption.According to the catalyst used in the pyrolysis of the organosilicon high boiling residues,the catalytic pyrolysis technology of organosilicon high boiling residues can be classified to aluminium-chloride-based catalytic pyrolysis technology,organic-amine-based catalytic pyrolysis technology,phosphorus-palladium-coordination-compounds-based catalytic pyrolysis technology,phosphate-based catalytic pyrolysis technology,transition metal and transition metal compounds-based catalytic pyrolysis technology,molecular sieve and activated carbon-based catalytic pyrolysis technology.The characteristics and development status and trend of the catalytic pyrolysis technologies of the organosilicon high boiling residues were studied to provide support for the resource utilization treatment of organosilicon high boiling residues.It can be shown from the study that the organic-amine-based catalytic pyrolysis technology has more advantage than other technologies,and is development trend and hotspot of the catalytic pyrolysis technology of the organosilicon high boiling residues,has good development prospects.Therefore,the organic-amine-based catalytic pyrolysis technology should be developed and utilized.

关 键 词：有机硅高沸物 催化裂解 无害化 资源化 处理技术 

分 类 号：TQ264.1[化学工程—有机化工]