碳纤维增强碳基复合材料的介电性能对应力的自感知  

Self-Sensing Behavior of Carbon Fiber Reinforced Carbon Matrix Composite Based on Dielectric Behavior

作　　者：席翔 李海龙[1] 陈友元 裴景奇 廖城坤 薛琳 储洪强 冉千平[2,4] Xiang Xi;Hailong Li;Youyuan Chen;Jingqi Pei;Chengkun Liao;Lin Xue;Hongqiang Chu;Qianping Ran(College of Civil and Transportation Engineering,Hohai University,Nanjing 210098,China;State Key Laboratory of High Performance Civil Engineering Materials,Jiangsu Research Institute of Building Science Co.Ltd.,Nanjing 210008,China;College of Materials Science and Engineering,Hohai University,Changzhou 213000,China;School of Materials Science and Engineering,Southeast University,Nanjing 211189,China)

机构地区：[1]河海大学土木与交通学院,江苏南京210098 [2]江苏省建筑科学研究院有限公司高性能土木工程材料国家重点实验室,江苏南京210008 [3]河海大学材料科学与工程学院,江苏常州213000 [4]东南大学材料科学与工程学院,江苏南京211189

出　　处：《高分子材料科学与工程》2024年第5期115-124,共10页Polymer Materials Science & Engineering

基　　金：中央高校基本科研业务费专项资金(B240201072);国家自然科学基金资助项目(52079048);江苏省重点研发计划(BE2020780)。

摘　　要：碳纤维增强碳基复合材料(C/C)具有优异的力学和导电性能,但其介电性能的报道较为罕见。文中采用LCR测量仪测量C/C的相对介电常数,采用电流源和纳伏表通过四电极法测量C/C的电阻率,研究了C/C的相对介电常数和电阻率随压应变的变化规律。研究表明,单位应变下相对介电常数的变化率(528±8)是电阻率变化率(111±5)的4.7倍,说明C/C复合材料的介电性能对其微观结构的改变更敏感。此外,压应变下C/C介电性能的增强归因于应变诱导的微缺陷提供了部分电子和空穴参与空间电荷极化的场所,以及压应变改善了极化连续性。单位压应变下增加的参与极化的电子或空穴的数量为(1.37±0.02)×10^(10)。C/C的相对介电常数低于碳纤维和石墨,可归因于碳基体中较高的孔隙率及较多的界面。Carbon fiber reinforced carbon matrix composites(C/C)are popular due to their excellent mechanical and conductive properties,while their dielectric behavior has received little attention.The LCR meter was used to measure the relative permittivity of C/C.The resistivity was measured by current source and nano-voltage meter combined with four-probe method.The results show that the fractional change in relative permittivity per unit strain is 528±8,which is 375%higher than the fractional change in resistivity per unit strain,indicating that the dielectric behavior is more sensitive to changes in microstructures.In addition,the enhancement of dielectric behavior of C/C is due to compressive strain inducing micro defects,such as grain boundaries,interfaces,etc.,that provide sites for space polarization involving a fraction of electrons and holes;on the other hand,the polarization continuity of C/C is enhanced by compression.The increase in the number of electrons and holes that participate in polarization per unit compressive strain is(1.37±0.02)×10^(10).The relative permittivity of C/C is lower than both carbon fiber and graphite due to high porosity and interfaces.

关 键 词：碳纤维 复合材料 介电性能 自感知 极化 介电常数 

分 类 号：TB332[一般工业技术—材料科学与工程]