炼油污水处理厂二沉出水中溶解性有机物组分分析  

Characterization of four fractions of dissolved organic matters in secondary effluent of refinery wastewater treatment plant

作　　者：王鑫[1] 肖向群 吴倩 姜峻韬 宁潇宇 王庆宏[1] 陈春茂[1] WANG Xin;XIAO Xiangqun;WU Qian;JIANG Juntao;Ning Xiaoyu;WANG Qinghong;CHENChunmao(State Key Laboratory of Heavy Oil Processing,College of Chemical Engineering and Environment,China University of Petroleum-Beijing,Beijing 102249,China;Luoyang R&D Center of Technology,Sinopec Engineering(Croup)Co.Ltd.,Luoyang 471003,China;State Key Laboratory of Petroleum Pollution Control,CNPC Research Institute of Safety&Environment Technology,Beijing 102206,China)

机构地区：[1]中国石油大学(北京)化学工程与环境学院,重质油国家重点实验室,北京102249 [2]中石化炼化工程(集团)股份有限公司洛阳技术研发中心,洛阳471003 [3]中国石油集团安全环保技术研究院有限公司,石油石化污染物控制与处理国家重点实验室,北京102206

出　　处：《环境工程学报》2024年第4期1096-1103,共8页Chinese Journal of Environmental Engineering

基　　金：中国石油科技创新基金(2020D-5007-0505);中国石油大学(北京)科研启动基金(2462021YJRC016);国家自然科学基金面上项目(22176220)。

摘　　要：使用MCX/MAX萃取柱对炼油污水处理厂二沉池出水中的溶解性有机物(DOM)进行分离,获得疏水酸性组分(HOA)、疏水碱性组分(HOB)、疏水中性组分(HON)和亲水物质(HIS)4种亚组分。使用三维荧光光谱和电喷雾-傅里叶变换离子回旋共振质谱对各组分进行了组成表征,结果表明:二沉出水中存在酚类物质和石油类物质的特征荧光峰;HOA组分中化合物类型较多,主要为CHOS类物质;HOB组分中检测到的物质较少,主要为O_(3)S_(1)物质;HON组分中有较多的CHOS、CHON和CHO类物质。以上研究结果可为炼油污水处理工艺优化和外排水环境影响评估提供参考。The dissolved organic matter(DOM)in the effluent from the secondary effluent of a refinery wastewater treatment plant was separated by MCX/MAX extraction column,and four sub-components including hydrophobic acidic component(HOA),hydrophobic alkaline component(HOB),hydrophobic neutral component(HON)and hydrophilic substance(HIS)were obtained.3D-EEM and ESI FT-ICR MS were used to analyze each component.The results showed that specific fluorescence peaks of phenolic substances and petroleum substances existed in the refined wastewater,there were more compounds in HOA component,which mainly was CHOS substances;less substances were detected in HOB component,which mainly was O_(3)S_(1) substances,and more CHOS,CHON and CHO substances were observed in HON component.This study makes an in-depth analysis of DOM in the effluent of refined wastewater,providing a reference for treatment process optimization and environmental impact assessment of external drainage of refinery wastewater.

关 键 词：炼油污水 二沉出水 三维荧光 分子组成 

分 类 号：X703[环境科学与工程—环境工程]