高分子化学综合实验设计:三嗪基多孔聚合物的合成及其染料吸附性能  

Comprehensive Experiment Design of Polymer Chemistry:Synthesis of a Triazine-based Porous Polymer and Its Dye Adsorption Performance

作　　者：董彬 周慧茹 郭玉盈 刘昱昊 DONG Bin;ZHOU Hui-ru;GUO Yu-ying;LIU Yu-hao(School of Chemical Engineering and Technology,China University of Mining and Technology,Xuzhou 221116,China)

机构地区：[1]中国矿业大学化工学院,徐州221116

出　　处：《高分子通报》2024年第7期967-973,共7页Polymer Bulletin

基　　金：应用化学国家一流本科专业建设点,江苏省大学生创新创业训练计划校企合作基金项目(基金号202210290168Y)。

摘　　要：基于三嗪基多孔聚合物的合成及其应用于染料吸附的创新性成果设计了综合实验。以碘化钾为催化剂,大大缩短了亲核取代反应合成三嗪基多孔聚合物P(CC-CH)的反应时间,并测定其染料吸附性能,使学生深入认识芳杂环亲核取代反应、催化剂的重要性以及染料废水处理方法,掌握红外光谱仪、X射线衍射仪、紫外-可见分光光度计等表征手段,提高学生的环境污染与防治意识和利用所学知识解决社会实际问题的能力。本实验学时紧凑,仪器表征简便,试剂成本低廉,适合在化学或相关专业的本科实验教学中推广。Based on the innovative achievement in the preparation of a triazine-based porous polymer and its application in dye adsorption,a comprehensive experiment is designed.Potassium iodide was used as the catalyst,greatly shortening the reaction time of nucleophilic substitution reaction to synthesize the triazine-based porous polymer P(CC-CH).Together with its dye adsorption behavior,students can have a deep understanding of the aromatic nucleophilic substitution reaction,the importance of catalyst,and the dye wastewater treatment.Meanwhile,students will master the use of infrared spectrometer,X-ray diffractometer,and UV-Vis spectrophotometer,be awareness of environmental pollution and prevention,as well as improve the ability of using knowledge to solve practical social problems.Considering compact class hours as well as convenient instruments and low-cost reagents used,this experiment is suitable for promotion in undergraduate experiments of chemistry or other related majors.

关 键 词：多孔聚合物 科研成果转化 染料吸附 芳杂环亲核取代反应 综合化学实验 

分 类 号：X703[环境科学与工程—环境工程] TQ424[化学工程] TQ317