有机铝催化的不饱和化合物硼氢化反应  

Hydroboration of Unsaturated Substrates Catalyzed by Organoaluminum

作　　者：马应花 刘鑫 冯雪兰 郭燕 刘翔宇[1] 丁毅 MA Yinghua;LIU Xin;FENG Xuelan;GUO Yan;LIU Xiangyu;DING Yi(School of Chemistry and Chemical Engineering,Ningxia University,Yinchuan 750021,China;China Explosive Materials Trade Association,Beijing 100089,China)

机构地区：[1]宁夏大学化学化工学院,宁夏银川750021 [2]中国爆破器材行业协会,北京100089

出　　处：《宁夏工程技术》2024年第2期115-123,131,共10页Ningxia Engineering Technology

基　　金：宁夏回族自治区教育厅高等学校科学研究项目(NYG2022024);宁夏自然科学基金项目(2023AAC03008;2022AAC03041)。

摘　　要：开发价廉质优、绿色环保、原子经济的催化剂是当前乃至今后化学工作者需要突破的难题之一。过渡金属配合物因其配合物中心金属出色的氧化还原能力而备受青睐,作为催化剂已被广泛应用于有机反应中。与过渡金属相比,主族金属催化剂被认为是商业用途广泛且环境友好的新型催化剂,随着主族金属有机化合物(尤其是低价态化合物)的不断开发与研究,主族金属有机化合物的催化性能及应用引起了广泛关注。近年来,β-二亚胺铝二氢催化性能的开创性研究,使探索绿色有机铝催化剂的研究得到了迅速的发展。本文综述了有机铝催化不饱和化合物的硼氢化反应,系统地总结了其催化机理和反应历程,并对有机铝催化剂进行了分析和展望,以期为开发主族元素有机催化剂并研究其催化机理提供素材。Green,eco-friendly and atomic economy has become a hot topic in chemical research,and the development of inexpensive,high quality,green,eco-friendly and atomic economy catalysts is one of challenges that chemists need to break through in the present and future.The transition metal complexes are highly favored because of the excellent redox ability of the center metal,and have been widely used as catalysts in the organic reactions.Compared with transition metal complexes,the main group metal catalysts are considered as new catalysts with wide commercial applications and environmental friendliness.With the continuous development and research of main group organometallics(especially the low valence organometallics),the catalytic properties and applications of main group organometallics have attracted wide attention.In recently,with the pioneering discovery ofβ-diimide aluminum dihydrogen catalytic performance,the research on exploring green organoaluminum catalysts has been developed rapidly.In this paper,the hydroboration of unsaturated compounds catalyzed by organoaluminum is reviewed,and its catalytic mechanism and reaction process are systematically summarized.The analysis and prospect of organoaluminum catalysts are also presented,in order to provide material for the development of main group element organic catalysts and the study of their catalytic mechanism.

关 键 词：有机铝 不饱和化合物 硼氢化反应 绿色催化剂 催化机理 

分 类 号：TB34[一般工业技术—材料科学与工程] O643.36[理学—物理化学] O627.31[理学—化学]