聚己内酯基准聚轮烷的构建技术  

Construction technology of polypseudorotaxanes based on polycaprolactone

作　　者：尹晓璇 禚可欣 王若华 陈健壮[1] 林绍梁[1] YIN Xiao-xuan;ZHUO Ke-xin;WANG Ruo-hua;CHEN Jian-zhuang;LIN Shao-liang(National Demonstration Center for Experimental Material Education,School of Materials Science and Engineering,East China University of Science and Technology,Shanghai 200237,China)

机构地区：[1]华东理工大学材料科学与工程学院,材料国家级实验教学示范中心,上海200237

出　　处：《化学工程师》2024年第7期59-63,共5页Chemical Engineer

基　　金：上海市自然科学基金面上项目(21ZR1415900);上海市教育系统工会理论研究课题(2021GHL037);大学生创新创业训练计划(202310251118X,S202310251101,X202210251412X)。

摘　　要：准聚轮烷作为一种新型超分子体系,已被广泛应用于生物传感器、分子机器及药物控释载体等诸多领域。本文首先简要介绍了聚己内酯(PCL)基准聚轮烷的研究意义,然后基于不同的环状主体对PCL基准聚轮烷的构建技术进行了分类和举例介绍,最后对PCL基准聚轮烷的发展前景进行了展望。本文工作可为功能性超分子聚合物的研究提供借鉴。As a new type of supramolecular system,polypseudorotaxanes have been widely used in many fields such as biosensors,molecular machines,and controlled release drug carriers.Firstly,the research significance of polycaprolactone-based polypseudorotaxanes was briefly introduced.Then,the construction technologies of polycaprolactone-based polypseudorotaxane were classified and examples provided based on different cyclic hosts.Finally,the development prospects of polycaprolactone-based polypseudorotaxanes were prospected.This work can provide reference for the research of functional supramolecular polymers.

关 键 词：聚己内酯 环糊精 冠醚 柱芳烃 准聚轮烷 

分 类 号：G644.5[文化科学—高等教育学]