Potentially Practical Catalytic Systems for Olefin-Polar Monomer Coordination Copolymerization  

作　　者：Chen Tan Min Chen Chen Zou Changle Chen 

机构地区：[1]Institutes of Physical Science and Information Technology,Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education,Key Laboratory of Environment-Friendly Polymeric Materials of Anhui Province,Anhui University,Hefei,Anhui 230601 [2]CAS Key Laboratory of Soft Matter Chemistry,Department of Polymer Science and Engineering,University of Science and Technology of China,Hefei 230026

出　　处：《CCS Chemistry》2024年第4期882-897,共16页中国化学会会刊（英文）

基　　金：supported by the National Key R&D Program of China(grant no.2021YFA1501700);the National Natural Science Foundation of China(grant nos.52025031,22001004,52373002,U1904212,and 52203016).

摘　　要：Studies on transition-metal catalyzed olefin-polar monomer coordination copolymerization and their resulting polar-functionalized polyolefin materials have attracted attention from both academia and industry.After decades of research,recent developments in a variety of high-performance catalytic systems have shown that this field is on the brink of industrialization.This review summarizes representative olefin-polar monomer coordination copolymerization catalyst systems that may be suitable for industrial polyolefin production via homogeneous solution-phase processes or heterogeneous gas-phase/slurry-phase processes.

关 键 词：olefin copolymerization polar monomer catalyst solution polymerization heterogeneous 

分 类 号：O64[理学—物理化学]