A Fluorinated,Ion-Conducting and Adaptive Supramolecular Polymer Protective Layer for Stabilizing Lithium Metal Anodes  

作　　者：Tao Chen Bo Qin Yuncong Liu Zhekai Jin Haiping Wu Chao Wang Xi Zhang 

机构地区：[1]Institute of Smart City and Intelligent Transportation,Southwest Jiaotong University,Chengdu 610032 [2]Key Lab of Organic Optoelectronics and Molecular Engineering,Department of Chemistry,Tsinghua University,Beijing 100084 [3]Department of Battery Technology,BYD Shanghai Co.,Ltd.,Shanghai 201611

出　　处：《CCS Chemistry》2024年第5期1157-1164,共8页中国化学会会刊（英文）

基　　金：National Natural Science Foundation of China(grant no.22075164);Fundamental Research Funds for the Central Universities,Southwest Jiaotong University(grant no.2682023CX005).

摘　　要：Perfluoropolyether(PFPE)is a promising material for protective coatings on Li metal anodes due to its chemical inertness and minimal swelling in electrolytes.However,a conventional PFPE coating with poor ionic conductivity and mechanical stability is still not satisfactory for long-term cycling of Li anodes.Here,we design and synthesize an adaptive and high-conductivity supramolecular polymer(PFPE-EG-I).This polymer is constructed from PFPE chains,ethylene glycol(EG)segments,and hydrogen-bonding moieties derived from isophoronediisocyanate,serving as a multifaceted artificial solid electrolyte interphase(SEI).The incorporated EG segments enhance the Li+conductivity of the SEI,and the hydrogen-bonding units introduce a dynamic self-adaptive behavior to the polymer matrix.A solution-processed PFPE-EG-I coating is demonstrated to promote uniform Li deposition and mitigate side reactions between Li and the electrolyte.Consequently,this leads to enhanced coulombic efficiency and prolonged cycle longevity in lithium metal batteries(LMBs).The innovative design of this multifunctional artificial SEI offers a promising avenue for the realization of dendrite-free Li anodes,paving the way for the advancement of high-performance LMBs.

关 键 词：supramolecular polymers BATTERIES lithium anodes artificial solid electrolyte interphase PERFLUOROPOLYETHER 

分 类 号：O631.5[理学—高分子化学] TM912[理学—化学]