Mild construction of N-fused polycyclic compounds via Rh(Ⅲ)/EosinY co-catalyze C—H activation  

作　　者：Zhouping Wu Guanghui Lv Zheng Lin Jiangyan Tang Jian Chen Jianghong Liu Li Hai Yong Wu 

机构地区：[1]Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry and Sichuan Province,Sichuan Engineering Laboratory for Plant-Sourced Drug and Sichuan Research Center for Drug Precision Industrial Technology,West China School of Pharmacy,Sichuan University,Chengdu 610041,China [2]Department of Pharmacy,Taihe Hospital,Hubei University of Medicine,No.32 South Renmin Road,Shiyan 442000,China

出　　处：《Green Synthesis and Catalysis》2024年第2期108-111,共4页绿色合成与催化（英文）

基　　金：the support from Sichuan Science and Technology Program(No.2020YJ0221).

摘　　要：The construction of N-fused polycyclic compounds at room temperature via the combination of transition-metal catalyst and photocatalyst has been reported.This novel work has successfully realized LED irradiated C—H activation of iodonium ylides.The strategy shows wide substrate scope and ideal functional group tolerance.Our work would be useful for the construction of various heterocyclic compounds.

关 键 词：N-fused polycyclic compounds C—H activation Rh(Ⅲ)catalyst and photocatalyst Iodonium ylides Energy transfer process 

分 类 号：O64[理学—物理化学]