Electrooxidative trifunctionalization of alkenes with N-chlorosuccinimide and ArSSAr/ArSH to α,β-dichloride arylsulfoxides  

作　　者：Guohui Qin Renjie Wang Zhen Cheng Yonghong Zhang Bin Wang Yu Xia Weiwei Jin Chenjiang Liu 

机构地区：[1]Urumqi Key Laboratory of Green Catalysis and Synthesis Technology,Key Laboratory of Oil and Gas Fine Chemicals,Ministry of Education&Xinjiang Uygur Autonomous Region,State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources,College of Chemistry,Xinjiang University,Urumqi 830017,China

出　　处：《Green Synthesis and Catalysis》2024年第2期131-135,共5页绿色合成与催化（英文）

基　　金：the National Natural Science Foundation of China(Nos.21702175,21961037,22061040 and 22161044);the Program for Tianshan Innovative Research Team of Xinjiang Uygur Autonomous Region(No.2021D14011);the Natural Science Foundation of Xinjiang Uygur Autonomous Region(No.2020D01C077)for support of this research.

摘　　要：An unprecedented electrochemical oxidative trifunctionalization of olefins with diaryl disulfides/aryl thiols and N-chlorosuccinimide in an aqueous system is developed.Two C-Cl bonds,one C-S bond,and one S=O bond are produced simultaneously in one step from simple and commercially available starting materials with clean energy.This tandem methodology features as mild reaction conditions,transition metal and additional oxidant free,broad substrate scope,good functional group compatibility,and gram scale preparation.

关 键 词：ELECTROOXIDATION Alkenes functionalization Vicinal dichlorination SULFOXIDATION Tandem reaction 

分 类 号：O62[理学—有机化学]