Liquid Phase Exfoliation of 2D Materials and Its ElectrochemicalApplications in the Data-Driven Future  

作　　者：Panwad Chavalekvirat Wisit Hirunpinyopas Krittapong Deshsorn Kulpavee Jitapunkul Pawin Iamprasertkun 

机构地区：[1]School of Bio-Chemical Engineering and Technology,Sirindhorn International Institute of Technology,Thammasat University,Pathum Thani 12120,Thailand,Research Unit in Sustainable Electrochemical Intelligent,Thammasat University,Pathum Thani 12120,Thailand [2]Department of Chemistry,Faculty of Science,Kasetsart University,Bangkok 10900,Thailand [3]Department of Chemical Engineering,Faculty of Engineering,Kasetsart University,Bangkok 10900,Thailand

出　　处：《Precision Chemistry》2024年第7期300-329,共30页精准化学（英文）

基　　金：This project is funded by National Research Council of Thailand(NRCT)under Contract N42A660942.P.C.acknowledges the ETS scholarship awarded by Sirindhorn International Institute of Technology,Thammasat University.P.C.thanks Mrs.Siriporn Chavalekvirat,Mr.Decha Jitkla,Mr.Tule Chavalekvirat,Ms.Aritsa Bunpheng,and Mr.Na Jaemin for unconditional support and love.

摘　　要：The electrochemical properties of 2D materials,particularly transition metal dichalcogenides(TMDs),hinge ontheir structural and chemical characteristics.To be practicallyviable,achieving large-scale,high-yield production is crucial,ensuring both quality and electrochemical suitability forapplications in energy storage,electrocatalysis,and potentialbasedionic sieving membranes.A prerequisite for success is a deepunderstanding of the synthesis process,forming a critical linkbetween materials synthesis and electrochemical performance.Thisreview extensively examines the liquid-phase exfoliation technique,providing insights into potential advancements and strategies tooptimize the TMDs nanosheet yield while preserving theirelectrochemical attributes.The primary goal is to compiletechniques for enhancing TMDs nanosheet yield through direct liquid-phase exfoliation,considering parameters like solvents,surfactants,centrifugation,and sonication dynamics.Beyond addressing the exfoliation yield,the review emphasizes the potentialimpact of these parameters on the structural and chemical properties of TMD nanosheets,highlighting their pivotal role inelectrochemical applications.Acknowledging evolving research methodologies,the review explores integrating machine learning anddata science as tools for understanding relationships and key characteristics.Envisioned to advance 2D material research,includingthe optimization of graphene,MXenes,and TMDs synthesis for electrochemical applications,this compilation charts a coursetoward data-driven techniques.By bridging experimental and machine learning approaches,it promises to reshape the landscape ofknowledge in electrochemistry,offering a transformative resource for the academic community.

关 键 词：Liquid Phase Exfoliation 2D Materials Transition Metal Dichalcogenides TMDS Size Selection ELECTROCHEMISTRY Energy Storage Ionic Sieving Machine Learning 

分 类 号：TB30[一般工业技术—材料科学与工程]