多相催化氧化伯醇制备羧酸的研究进展  

Research progress on preparation of carboxylic acids from heterogeneous catalytic oxidation of primary alcohols

作　　者：薛飞 刘梦力 廖敏 李臻[1] 夏春谷[1] 王金棒 XUE Fei;LIU Mengli;LIAO Min;LI Zhen;XIA Chungu;WANG Jinbang(State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000,Gansu,China;Ganzhou Branch of Jiangxi Tobacco Corporation,Ganzhou 341000,Jiangxi,China;Zhengzhou Tobacco Research Institute of CNTC,Zhengzhou 450001,Henan,China)

机构地区：[1]中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室,甘肃兰州730000 [2]江西省烟草公司赣州市公司,江西赣州341000 [3]中国烟草总公司郑州烟草研究院,河南郑州450001

出　　处：《精细化工》2024年第7期1393-1403,共11页Fine Chemicals

基　　金：国家烟草专卖局、中国烟草总公司首席科学家创新专项项目(602022CK0550)。

摘　　要：伯醇催化氧化制羧酸是有机合成中极为重要的转化过程,具有广泛的应用前景。对于多相催化体系,高效催化剂的制备一直是研究的热点和难点。该文对近年来涉及多相催化氧化伯醇制备羧酸的文献进行了全面的梳理。从单金属及其氧化物和双金属及其氧化物基催化剂,以及是否采用载体等角度系统评估了伯醇氧化多相催化剂的发展现状和趋势;介绍了杂多酸催化和绿色催化的研究进展;展望了多相催化在工业应用中的发展前景和挑战。The catalytic oxidation of primary alcohols to carboxylic acids is an extremely important transformation process in organic synthesis,with a wide range of application scenarios.For heterogeneous catalytic oxidation systems,the preparation of efficient catalysts has always been a hot and difficult research topic.Here,a comprehensive review of recent literature on the preparation of carboxylic acids through heterogeneous catalytic oxidation of primary alcohols was presented.The development status and trends of heterogeneous catalysts for the oxidation of primary alcohols were systematically reviewed in terms of single metals and their oxides as well as bimetals and their oxides with or without support.The research progress on heteropoly acid catalysis and green catalysis was then introduced.Finally,the prospects and challenges of heterogeneous catalysis in industrial applications were discussed.

关 键 词：伯醇 催化氧化 多相催化 羧酸 金属催化剂 金属氧化物催化剂 

分 类 号：TQ426[化学工程] TQ225